This HTML5 document contains 55 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n11http://linked.opendata.cz/resource/domain/vavai/projekt/
n4http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n9http://linked.opendata.cz/ontology/domain/vavai/
n17http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n18http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61388980%3A_____%2F10%3A00346803%21RIV11-GA0-61388980/
n13http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n12http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n8http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n7http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n6http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F10%3A00346803%21RIV11-GA0-61388980
rdf:type
n9:Vysledek skos:Concept
dcterms:description
The arrangement of porphyrin molecules in the interlayer space of layered double hydroxides (LDH) has been studied by a combination of experimental techniques and molecular dynamics simulations. Intercalation of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrins (TPPS) into ZnRAl and MgRAl LDH hosts led to a gallery height of about 15.5 angstrom that is comparable with the size of the porphyrin molecules. The porphyrin sulfonate groups arc located at about 4 angstrom from the center of the hydroxide layers that is consistent with hydrogen bonding interactions between the sulfonate groups and OH groups of the layers. The aromatic ring system in the middle of the gallery is rather disordered A large number of in-plane diffraction lines suggests that the rigidity of the porphyrin framework has a beneficial effect on the layer ordering. The arrangement of porphyrin molecules in the interlayer space of layered double hydroxides (LDH) has been studied by a combination of experimental techniques and molecular dynamics simulations. Intercalation of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrins (TPPS) into ZnRAl and MgRAl LDH hosts led to a gallery height of about 15.5 angstrom that is comparable with the size of the porphyrin molecules. The porphyrin sulfonate groups arc located at about 4 angstrom from the center of the hydroxide layers that is consistent with hydrogen bonding interactions between the sulfonate groups and OH groups of the layers. The aromatic ring system in the middle of the gallery is rather disordered A large number of in-plane diffraction lines suggests that the rigidity of the porphyrin framework has a beneficial effect on the layer ordering.
dcterms:title
Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement
skos:prefLabel
Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement
skos:notation
RIV/61388980:_____/10:00346803!RIV11-GA0-61388980
n3:aktivita
n12:P n12:Z
n3:aktivity
P(GA203/07/1424), P(GAP207/10/1447), Z(AV0Z40320502), Z(AV0Z40400503), Z(MSM0021620835), Z(MSM0021620857)
n3:cisloPeriodika
8
n3:dodaniDat
n6:2011
n3:domaciTvurceVysledku
n4:5799457 n4:7933665 n4:3009459 n4:3020452 n4:1374710
n3:druhVysledku
n14:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
280043
n3:idVysledku
RIV/61388980:_____/10:00346803
n3:jazykVysledku
n8:eng
n3:klicovaSlova
hydrotalcite-like compounds; molecular-dynamic simulations; photophysical properties
n3:klicoveSlovo
n13:hydrotalcite-like%20compounds n13:molecular-dynamic%20simulations n13:photophysical%20properties
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[C4DA0B4D419B]
n3:nazevZdroje
Chemistry of Materials
n3:obor
n7:CA
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
9
n3:projekt
n11:GAP207%2F10%2F1447 n11:GA203%2F07%2F1424
n3:rokUplatneniVysledku
n6:2010
n3:svazekPeriodika
22
n3:tvurceVysledku
Pospíšil, M. Kubát, Pavel Káfuňková, Eva Klementová, Mariana Lang, Kamil Taviot-Guého, Ch. Mosinger, Jiří Kovář, P. Bezdička, Petr
n3:wos
000276817200011
n3:zamer
n17:AV0Z40320502 n17:MSM0021620835 n17:AV0Z40400503 n17:MSM0021620857
s:issn
0897-4756
s:numberOfPages
10