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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F09%3A00332205%21RIV10-MSM-61388980
rdf:type
skos:Concept n18:Vysledek
dcterms:description
New boron substituted cobalta bis(dicarbollide)(1-) ion (1) derivatives of formula [(8,80-(RPhP(O)(CH2)n-C(O) N)<(1,2-C2B9H10)(2)-3,3'-Co] (R = Ph or C8H17, n = 1, 3a, 3b; R = Ph, n = 2, 3c), [(8-(Ph2P(O)CH2-C(O)NR)(1,2-C2B9H10))(1',2'-C2B9H11)-3,3'-Co] (R-1 = H, C2H5, CH2C6H5, 5a-c) and [(8-((RPhP)-R-2(O)CH2C(O)-N( R-1)CH2-1,2-C2B9H10))(8'-CH3O-1',2'-C2B9H10)-3,3'-Co] (R-1 = Benzyl, R-2 = Ph or C8H17, 7a,b) were prepared with the aim to develop a new class of efficient extraction agents for partitioning of polyvalent f-block elements, i.e. lanthanides and actinides from high-level activity nuclear waste. The anionic ligands were characterized by multinuclear NMR spectroscopy and MS, the structures of Cs3a and the calcium complex of 7a were determined by X-ray diffraction analysis. The crystallographic study of the Cs3a proved a formation of linear chains in the structure, where the metal cation is coordinated by oxygen atoms of the CMPO terminal groups. New boron substituted cobalta bis(dicarbollide)(1-) ion (1) derivatives of formula [(8,80-(RPhP(O)(CH2)n-C(O) N)<(1,2-C2B9H10)(2)-3,3'-Co] (R = Ph or C8H17, n = 1, 3a, 3b; R = Ph, n = 2, 3c), [(8-(Ph2P(O)CH2-C(O)NR)(1,2-C2B9H10))(1',2'-C2B9H11)-3,3'-Co] (R-1 = H, C2H5, CH2C6H5, 5a-c) and [(8-((RPhP)-R-2(O)CH2C(O)-N( R-1)CH2-1,2-C2B9H10))(8'-CH3O-1',2'-C2B9H10)-3,3'-Co] (R-1 = Benzyl, R-2 = Ph or C8H17, 7a,b) were prepared with the aim to develop a new class of efficient extraction agents for partitioning of polyvalent f-block elements, i.e. lanthanides and actinides from high-level activity nuclear waste. The anionic ligands were characterized by multinuclear NMR spectroscopy and MS, the structures of Cs3a and the calcium complex of 7a were determined by X-ray diffraction analysis. The crystallographic study of the Cs3a proved a formation of linear chains in the structure, where the metal cation is coordinated by oxygen atoms of the CMPO terminal groups.
dcterms:title
Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste
skos:prefLabel
Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste Cobalt bis(dicarbollide) ions functionalized by CMPO-like groups attached to boron by short bonds; efficient extraction agents for separation of trivalent f-block elements from highly acidic nuclear waste
skos:notation
RIV/61388980:_____/09:00332205!RIV10-MSM-61388980
n3:aktivita
n6:Z n6:P
n3:aktivity
P(GA104/05/2667), P(GA104/09/0668), P(IAA400310613), P(LC523), Z(AV0Z40320502), Z(MSM0021620857)
n3:cisloPeriodika
11
n3:dodaniDat
n13:2010
n3:domaciTvurceVysledku
n4:2753847 n4:5578221 n4:2927640 n4:8071845
n3:druhVysledku
n11:J
n3:duvernostUdaju
n5:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
307433
n3:idVysledku
RIV/61388980:_____/09:00332205
n3:jazykVysledku
n10:eng
n3:klicovaSlova
carboranes; metallacarbaboranes; liquid-liquid extraction
n3:klicoveSlovo
n14:carboranes n14:metallacarbaboranes n14:liquid-liquid%20extraction
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[EF9760FE0845]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n9:CA
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
7
n3:projekt
n7:LC523 n7:IAA400310613 n7:GA104%2F05%2F2667 n7:GA104%2F09%2F0668
n3:rokUplatneniVysledku
n13:2009
n3:svazekPeriodika
694
n3:tvurceVysledku
Kvíčalová, Magdalena Šícha, Václav Císařová, I. Lučaníková, M. Grüner, Bohumír Selucký, P. Plešek, Jaromír
n3:wos
000264778500017
n3:zamer
n15:AV0Z40320502 n15:MSM0021620857
s:issn
0022-328X
s:numberOfPages
12