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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F06%3A00050975%21RIV07-GA0-61388980
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Room-temperature chlorination of the dicarbaborane nido-5,6-C2B8H12 ( 1) with CCl4 in the presence of anhydrous AlCl3 yielded a mixture of 7-Cl-5,6-C2B8H11 (7-Cl-1) ( yield 34 percent), 4-Cl-5,6-C2B8H11 (4- Cl-1) ( yield 20 percent), 3-Cl-5,6-C2B8H11 (3- Cl-1) ( yield 21 percent), and 3,4-Cl-2-5,6- C2B8H10 (3,4- Cl-2- 1) ( yield 26 percent), while a trisubstituted derivative, 3,4,7-Cl-3- 5,6-C2B8H9 (3,4,7-Cl-3- 1) ( yield 80 percent), was isolated as a sole product at reflux. Room-temperature chlorination of the dicarbaborane nido-5,6-C2B8H12 ( 1) with CCl4 in the presence of anhydrous AlCl3 yielded a mixture of 7-Cl-5,6-C2B8H11 (7-Cl-1) ( yield 34 percent), 4-Cl-5,6-C2B8H11 (4- Cl-1) ( yield 20 percent), 3-Cl-5,6-C2B8H11 (3- Cl-1) ( yield 21 percent), and 3,4-Cl-2-5,6- C2B8H10 (3,4- Cl-2- 1) ( yield 26 percent), while a trisubstituted derivative, 3,4,7-Cl-3- 5,6-C2B8H9 (3,4,7-Cl-3- 1) ( yield 80 percent), was isolated as a sole product at reflux. Elektrofilní halogenace nido-5,6- C2B8H12.
dcterms:title
Elektrofilní halogenace nido-5,6- C2B8H12 Electrophilic halogenation of nido-5,6-C2B8H12 Electrophilic halogenation of nido-5,6-C2B8H12
skos:prefLabel
Electrophilic halogenation of nido-5,6-C2B8H12 Electrophilic halogenation of nido-5,6-C2B8H12 Elektrofilní halogenace nido-5,6- C2B8H12
skos:notation
RIV/61388980:_____/06:00050975!RIV07-GA0-61388980
n3:strany
1549;1556
n3:aktivita
n18:P n18:Z
n3:aktivity
P(GA203/05/2646), Z(AV0Z40320502)
n3:cisloPeriodika
11-12
n3:dodaniDat
n6:2007
n3:domaciTvurceVysledku
n12:2449285 n12:8606862 n12:1509640
n3:druhVysledku
n15:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
473841
n3:idVysledku
RIV/61388980:_____/06:00050975
n3:jazykVysledku
n14:eng
n3:klicovaSlova
boranes; dicarbaboranes; electrophilic substitutions
n3:klicoveSlovo
n9:electrophilic%20substitutions n9:dicarbaboranes n9:boranes
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[63AE78035A01]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communications
n3:obor
n8:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n17:GA203%2F05%2F2646
n3:rokUplatneniVysledku
n6:2006
n3:svazekPeriodika
71
n3:tvurceVysledku
Štíbr, Bohumil Bakardjiev, Mario Holub, Josef
n3:zamer
n13:AV0Z40320502
s:issn
0010-0765
s:numberOfPages
7