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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F05%3A00029913%21RIV06-MSM-61388980
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] Cage closure, together with the loss of two boron vertices, of [2,5-(eta(5)-C5Me5)(2)-10-Me-mu-2,5-H-)nido-2,5,1-Rh,CB6H8] (1) using an approximately molar equivalent of elemental iodine and excess triethylamine results in the formation of a new species [1,2-(eta 5-C5Me5)2-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (2), which is characterized by multinuclear NMR spectroscopy, mass spectrometry, and single-crystal X-ray crystallography. The formation Of Compound 2 involves the elimination of a {B2CH3) moiety from I and an iodination of the single carbon vertex. Cage closure, together with the loss of two boron vertices, of [2,5-(eta(5)-C5Me5)(2)-10-Me-mu-2,5-H-)nido-2,5,1-Rh,CB6H8] (1) using an approximately molar equivalent of elemental iodine and excess triethylamine results in the formation of a new species [1,2-(eta 5-C5Me5)2-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (2), which is characterized by multinuclear NMR spectroscopy, mass spectrometry, and single-crystal X-ray crystallography. The formation Of Compound 2 involves the elimination of a {B2CH3) moiety from I and an iodination of the single carbon vertex.
dcterms:title
An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]
skos:prefLabel
An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]
skos:notation
RIV/61388980:_____/05:00029913!RIV06-MSM-61388980
n3:strany
4967;4970
n3:aktivita
n13:P
n3:aktivity
P(LC523)
n3:cisloPeriodika
21-22
n3:dodaniDat
n7:2006
n3:domaciTvurceVysledku
Londesborough, Michael Geoffrey Stephen
n3:druhVysledku
n11:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
511952
n3:idVysledku
RIV/61388980:_____/05:00029913
n3:jazykVysledku
n16:eng
n3:klicovaSlova
boranes
n3:klicoveSlovo
n5:boranes
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[C5637349D8EE]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n10:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n8:LC523
n3:rokUplatneniVysledku
n7:2005
n3:svazekPeriodika
690
n3:tvurceVysledku
Carr, M. J. Kennedy, D. J. Londesborough, Michael Geoffrey Stephen
s:issn
0022-328X
s:numberOfPages
4