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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F05%3A00021607%21RIV06-AV0-61388980
rdf:type
n15:Vysledek skos:Concept
dcterms:description
A review on cluster-borane analogues of the cyclopentadienide anion (Cp) and ferrocene is presented. Analogues of Cp that have been so far isolated and characterised are the 11-vertex triheteroboranes of general structure [nido-E3B8H8](-) (where E = CH or P and their combinations, the molecules of which contain an open pentagonal face. These anions were used as effective ligands for the preparation of %22half- and full-sandwich%22 complexes [CpFeE3B8H8] and [Fe(E3B8H8)(2)], respectively - analogues of ferrocene. Developments in this area of cluster-borane chemistry that include recent results in the synthesis and Fe-complexation reactions of 11-vertex tricarbaboranes (tricarbollides), phosphadicarbollides, and diphosphacarbollides are the subject of this work. Ve formě přehledného referátu jsou diskutovány nové výsledky v chemii klastrových boranových analogů cyklopentadienylového aniontu a ferrocenu, které obsahují trikarbaboranové a fosfakarboranové sloučeniny jako ligandy. A review on cluster-borane analogues of the cyclopentadienide anion (Cp) and ferrocene is presented. Analogues of Cp that have been so far isolated and characterised are the 11-vertex triheteroboranes of general structure [nido-E3B8H8](-) (where E = CH or P and their combinations, the molecules of which contain an open pentagonal face. These anions were used as effective ligands for the preparation of %22half- and full-sandwich%22 complexes [CpFeE3B8H8] and [Fe(E3B8H8)(2)], respectively - analogues of ferrocene. Developments in this area of cluster-borane chemistry that include recent results in the synthesis and Fe-complexation reactions of 11-vertex tricarbaboranes (tricarbollides), phosphadicarbollides, and diphosphacarbollides are the subject of this work.
dcterms:title
Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments Nový vývoj chemie klastrových boranových analogů cyklopentadienylového aniontu a ferrocenu
skos:prefLabel
Nový vývoj chemie klastrových boranových analogů cyklopentadienylového aniontu a ferrocenu Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments
skos:notation
RIV/61388980:_____/05:00021607!RIV06-AV0-61388980
n4:strany
2694;2700
n4:aktivita
n5:P n5:Z
n4:aktivity
P(GA203/05/2646), Z(AV0Z40320502)
n4:cisloPeriodika
11
n4:dodaniDat
n13:2006
n4:domaciTvurceVysledku
n7:2449285
n4:druhVysledku
n6:J
n4:duvernostUdaju
n10:S
n4:entitaPredkladatele
n16:predkladatel
n4:idSjednocenehoVysledku
515180
n4:idVysledku
RIV/61388980:_____/05:00021607
n4:jazykVysledku
n18:eng
n4:klicovaSlova
boron; boranes; carboranes
n4:klicoveSlovo
n9:carboranes n9:boranes n9:boron
n4:kodStatuVydavatele
CH - Švýcarská konfederace
n4:kontrolniKodProRIV
[7FC1BDA4EB4E]
n4:nazevZdroje
Journal of Organometallic Chemistry
n4:obor
n14:CA
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
1
n4:projekt
n17:GA203%2F05%2F2646
n4:rokUplatneniVysledku
n13:2005
n4:svazekPeriodika
690
n4:tvurceVysledku
Štíbr, Bohumil
n4:zamer
n12:AV0Z40320502
s:issn
0022-328X
s:numberOfPages
7