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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F05%3A00021014%21RIV06-AV0-61388980
rdf:type
skos:Concept n13:Vysledek
dcterms:description
Electrochemical properties of polymer gel electrolytes based on polymethylmethacrylate (PMMA) were studied by cyclic voltammetry and impedance spectroscopy using new solid-state PMMA-Cd-Cd2+ reference electrode. The suitable potential window of the PC-PMMA system was estimated from -0.2 to + 1.5 V versus Cd-Cd2+. New polymer gels containing ferrocene-ferricinium (Fc-Fc(+)) couple and other transition metal complexes were prepared by the direct polymerisation of methylmethacrylate (MMA) monomer and the solution of metal complex and supporting electrolyte in anhydrous aprotic solvent-propylene carbonate (PC). The half-wave potentials and apparent diffusion coefficients of used complexes and their dependence on the composition of the system (liquid or gel) were estimated. The results show that the PC-PMMA gel electrolyte can be described as a system of embedded solvent in the polymer network of PMMA without present monomer. Electrochemical properties of polymer gel electrolytes based on polymethylmethacrylate (PMMA) were studied by cyclic voltammetry and impedance spectroscopy using new solid-state PMMA-Cd-Cd2+ reference electrode. The suitable potential window of the PC-PMMA system was estimated from -0.2 to + 1.5 V versus Cd-Cd2+. New polymer gels containing ferrocene-ferricinium (Fc-Fc(+)) couple and other transition metal complexes were prepared by the direct polymerisation of methylmethacrylate (MMA) monomer and the solution of metal complex and supporting electrolyte in anhydrous aprotic solvent-propylene carbonate (PC). The half-wave potentials and apparent diffusion coefficients of used complexes and their dependence on the composition of the system (liquid or gel) were estimated. The results show that the PC-PMMA gel electrolyte can be described as a system of embedded solvent in the polymer network of PMMA without present monomer. Byla studována kinetika elektrochemických redoxních reakcí ferrocenu a komplexů kobaltu v prostředí polymerních gelových elektrolytů na bázi PMMA - propylenkarbonát. U komplexů byly v prostředí kapalného a gelového elektrolytu stanoveny difúzní koeficienty.
dcterms:title
Elektrochemické redoxní procesy v PMMA gelových elektrolytech – chování komplexů přechodných kovů The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes
skos:prefLabel
The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes Elektrochemické redoxní procesy v PMMA gelových elektrolytech – chování komplexů přechodných kovů
skos:notation
RIV/61388980:_____/05:00021014!RIV06-AV0-61388980
n5:strany
4469;4476
n5:aktivita
n16:P n16:Z
n5:aktivity
P(GA104/02/0731), P(KJB4813302), Z(AV0Z40320502)
n5:cisloPeriodika
22
n5:dodaniDat
n10:2006
n5:domaciTvurceVysledku
n14:8828288 n14:6867731
n5:druhVysledku
n17:J
n5:duvernostUdaju
n18:S
n5:entitaPredkladatele
n9:predkladatel
n5:idSjednocenehoVysledku
519933
n5:idVysledku
RIV/61388980:_____/05:00021014
n5:jazykVysledku
n11:eng
n5:klicovaSlova
polymer electrolyte; ferrocene; diffusion coefficient
n5:klicoveSlovo
n6:polymer%20electrolyte n6:diffusion%20coefficient n6:ferrocene
n5:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n5:kontrolniKodProRIV
[FAAB9784F051]
n5:nazevZdroje
Electrochimica acta
n5:obor
n7:CA
n5:pocetDomacichTvurcuVysledku
2
n5:pocetTvurcuVysledku
3
n5:projekt
n8:KJB4813302 n8:GA104%2F02%2F0731
n5:rokUplatneniVysledku
n10:2005
n5:svazekPeriodika
50
n5:tvurceVysledku
Reiter, Jakub Mička, Z. Vondrák, Jiří
n5:zamer
n15:AV0Z40320502
s:issn
0013-4686
s:numberOfPages
8