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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F04%3A00108166%21RIV%2F2005%2FAV0%2FA50005%2FN
rdf:type
n18:Vysledek skos:Concept
dcterms:description
Popsána je příprava a genese dvou nových sloučenin v 19-vrcholové iridaboranové řadě. Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom. Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom.
dcterms:title
Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM... Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM... Makropolyedrická borová chemie. Dvouelektronové variace intraklastrové vazebné intimity indukované ligandem.. Struktury 19-vrcholového ... a podobného karbenového komplexu
skos:prefLabel
Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM... Makropolyedrická borová chemie. Dvouelektronové variace intraklastrové vazebné intimity indukované ligandem.. Struktury 19-vrcholového ... a podobného karbenového komplexu Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM...
skos:notation
RIV/61388980:_____/04:00108166!RIV/2005/AV0/A50005/N
n3:strany
1521;1523
n3:aktivita
n13:P n13:Z
n3:aktivity
P(IAA4032701), Z(AV0Z4032918)
n3:cisloPeriodika
10
n3:dodaniDat
n4:2005
n3:domaciTvurceVysledku
n8:2449285 n8:9991492
n3:druhVysledku
n15:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
571975
n3:idVysledku
RIV/61388980:_____/04:00108166
n3:jazykVysledku
n12:eng
n3:klicovaSlova
carboranes; 19-vertex; boranes
n3:klicoveSlovo
n9:19-vertex n9:boranes n9:carboranes
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[18595B3EF07C]
n3:nazevZdroje
Dalton Transactions
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:projekt
n10:IAA4032701
n3:rokUplatneniVysledku
n4:2004
n3:svazekPeriodika
-
n3:tvurceVysledku
Kennedy, J. D. Perera, S. D. Jelínek, Tomáš Shea, S. L. Štíbr, Bohumil Thornton-Pett, M.
n3:zamer
n11:AV0Z4032918
s:issn
1477-9226
s:numberOfPages
3