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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F04%3A00106529%21RIV%2F2005%2FAV0%2FA50005%2FN
rdf:type
n3:Vysledek skos:Concept
dcterms:description
Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies. Článek popisuje tvorbu matallokarboranů uvedených v titulu článku společně s popisem metallokarboranu nesoucího málo se vyskytující Rh-H-Rh můstkový vodikový atom. Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies.
dcterms:title
Metallakarboránová chemie aniontu hypho-[6,7-C2B6H13](-) : příprava nových metallakarboránů s jedinečnými strukturami [5-Cp*-arachno-5,4,6-RhC2B6H12] a [2,5-(Cp*)2-10-Me-nido-2,5,1-Rh2CB6H9 : úplná rhodiová analoga arachno-4,6-C2B7H13 a nido-1-CB8H12 Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a... Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a...
skos:prefLabel
Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a... Metallakarboránová chemie aniontu hypho-[6,7-C2B6H13](-) : příprava nových metallakarboránů s jedinečnými strukturami [5-Cp*-arachno-5,4,6-RhC2B6H12] a [2,5-(Cp*)2-10-Me-nido-2,5,1-Rh2CB6H9 : úplná rhodiová analoga arachno-4,6-C2B7H13 a nido-1-CB8H12 Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a...
skos:notation
RIV/61388980:_____/04:00106529!RIV/2005/AV0/A50005/N
n7:strany
2702;2706
n7:aktivita
n8:Z n8:P
n7:aktivity
P(LN00A028), Z(AV0Z4032918)
n7:cisloPeriodika
16
n7:dodaniDat
n16:2005
n7:domaciTvurceVysledku
n10:2449285 Londesborough, Michael Geoffrey Stephen n10:4302834
n7:druhVysledku
n9:J
n7:duvernostUdaju
n18:S
n7:entitaPredkladatele
n13:predkladatel
n7:idSjednocenehoVysledku
573048
n7:idVysledku
RIV/61388980:_____/04:00106529
n7:jazykVysledku
n12:eng
n7:klicovaSlova
boranes; metallacarboranes; rhodium complex
n7:klicoveSlovo
n14:rhodium%20complex n14:metallacarboranes n14:boranes
n7:kodStatuVydavatele
CH - Švýcarská konfederace
n7:kontrolniKodProRIV
[677B3192D6B2]
n7:nazevZdroje
Journal of Organometalic Chemistry
n7:obor
n17:CA
n7:pocetDomacichTvurcuVysledku
3
n7:pocetTvurcuVysledku
4
n7:projekt
n15:LN00A028
n7:rokUplatneniVysledku
n16:2004
n7:svazekPeriodika
689
n7:tvurceVysledku
Císařová, I. Štíbr, Bohumil Janoušek, Zbyněk Londesborough, Michael Geoffrey Stephen
n7:zamer
n11:AV0Z4032918
s:issn
0022-328X
s:numberOfPages
5