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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F03%3A50033041%21RIV%2F2004%2FMSM%2FA50004%2FN
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis. Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis.
dcterms:title
Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.
skos:prefLabel
Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.
skos:notation
RIV/61388980:_____/03:50033041!RIV/2004/MSM/A50004/N
n3:strany
6115;6121
n3:aktivita
n15:Z n15:P
n3:aktivity
P(GA203/00/1042), P(GA203/01/0944), P(LN00A028), Z(AV0Z4032918)
n3:cisloPeriodika
24
n3:dodaniDat
n10:2004
n3:domaciTvurceVysledku
n6:2449285 n6:8679827 n6:5578221
n3:druhVysledku
n16:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n4:predkladatel
n3:idSjednocenehoVysledku
603813
n3:idVysledku
RIV/61388980:_____/03:50033041
n3:jazykVysledku
n17:eng
n3:klicovaSlova
boranes; carboranes; cluster compounds
n3:klicoveSlovo
n5:boranes n5:cluster%20compounds n5:carboranes
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[E2BDEE841A12]
n3:nazevZdroje
Chemistry A European Journal
n3:obor
n8:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
7
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n9:GA203%2F00%2F1042 n9:GA203%2F01%2F0944 n9:LN00A028
n3:rokUplatneniVysledku
n10:2003
n3:svazekPeriodika
9
n3:tvurceVysledku
Grüner, Bohumír Stopka, Pavel Kivekäs, R. Teixidor, F. Sillanpää, R. Vinas, C. Štíbr, Bohumil
n3:zamer
n18:AV0Z4032918
s:issn
0947-6539
s:numberOfPages
7