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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F02%3A50023007%21RIV%2F2003%2FAV0%2FA50003%2FN
rdf:type
skos:Concept n18:Vysledek
dcterms:description
A synthesis is described of the four C-halogenated 1-X-CB11H11- anions (X = I, Br, Cl, F) using N-halosuccinimides and N-fluorobis( benzenesulfonyl) amine as halogenating agents. The procedure yields only the desired product next to unreacted starting material. Regularities in the B-11 and C-13 NMR chemical shifts of singly halogenated icosahedral carboranes are summarized. A synthesis is described of the four C-halogenated 1-X-CB11H11- anions (X = I, Br, Cl, F) using N-halosuccinimides and N-fluorobis( benzenesulfonyl) amine as halogenating agents. The procedure yields only the desired product next to unreacted starting material. Regularities in the B-11 and C-13 NMR chemical shifts of singly halogenated icosahedral carboranes are summarized.
dcterms:title
C-halogenation of the closo-[CB11H12](-) anion. C-halogenation of the closo-[CB11H12](-) anion.
skos:prefLabel
C-halogenation of the closo-[CB11H12](-) anion. C-halogenation of the closo-[CB11H12](-) anion.
skos:notation
RIV/61388980:_____/02:50023007!RIV/2003/AV0/A50003/N
n3:strany
1025;1034
n3:aktivita
n10:P n10:Z
n3:aktivity
P(LN00A028), Z(AV0Z4032918)
n3:cisloPeriodika
7
n3:dodaniDat
n8:2003
n3:domaciTvurceVysledku
n9:4302834
n3:druhVysledku
n13:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n4:predkladatel
n3:idSjednocenehoVysledku
640520
n3:idVysledku
RIV/61388980:_____/02:50023007
n3:jazykVysledku
n17:eng
n3:klicovaSlova
boranes; boron clusters; carboranes
n3:klicoveSlovo
n5:boranes n5:boron%20clusters n5:carboranes
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[42D107C43802]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communication
n3:obor
n16:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n15:LN00A028
n3:rokUplatneniVysledku
n8:2002
n3:svazekPeriodika
67
n3:tvurceVysledku
Janoušek, Zbyněk Hilton, C. L. Michl, J. Schreiber, P. J.
n3:zamer
n7:AV0Z4032918
s:issn
0010-0765
s:numberOfPages
10