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Statements

Subject Item
n2:RIV%2F61388971%3A_____%2F13%3A00425874%21RIV14-AV0-61388971
rdf:type
skos:Concept n10:Vysledek
dcterms:description
This review is oriented toward the asymmetric transfer hydrogenation (ATH) of imines regarding mostly fundamental, yet important topics from the practical point of view. Development of analytical methods for the monitoring of ATH (i.e., kinetics and stereoselectivity) belongs to those topics, as well as studies on the influence of reaction conditions and structural variations on the reaction performance. The second part is devoted to the reaction mechanism with the emphasis on imine ATH and catalyst behaviour under acidic conditions. The review also addresses the asymmetric hydrogenation (AH) of ketones and imines using molecular hydrogen and the application of ATH in pharmaceutical projects. The contributions of our group to each area are included This review is oriented toward the asymmetric transfer hydrogenation (ATH) of imines regarding mostly fundamental, yet important topics from the practical point of view. Development of analytical methods for the monitoring of ATH (i.e., kinetics and stereoselectivity) belongs to those topics, as well as studies on the influence of reaction conditions and structural variations on the reaction performance. The second part is devoted to the reaction mechanism with the emphasis on imine ATH and catalyst behaviour under acidic conditions. The review also addresses the asymmetric hydrogenation (AH) of ketones and imines using molecular hydrogen and the application of ATH in pharmaceutical projects. The contributions of our group to each area are included
dcterms:title
Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes
skos:prefLabel
Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes
skos:notation
RIV/61388971:_____/13:00425874!RIV14-AV0-61388971
n10:predkladatel
n11:ico%3A61388971
n4:aktivita
n15:I n15:P
n4:aktivity
I, P(GA104/09/1497), P(GAP106/12/1276)
n4:cisloPeriodika
6
n4:dodaniDat
n16:2014
n4:domaciTvurceVysledku
n5:1927469
n4:druhVysledku
n14:J
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n7:predkladatel
n4:idSjednocenehoVysledku
98194
n4:idVysledku
RIV/61388971:_____/13:00425874
n4:jazykVysledku
n18:eng
n4:klicovaSlova
asymmetric hydrogenation; ruthenium; reaction conditions
n4:klicoveSlovo
n17:reaction%20conditions n17:asymmetric%20hydrogenation n17:ruthenium
n4:kodStatuVydavatele
CH - Švýcarská konfederace
n4:kontrolniKodProRIV
[035F4771E0E2]
n4:nazevZdroje
Molecules
n4:obor
n6:CC
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
6
n4:projekt
n8:GAP106%2F12%2F1276 n8:GA104%2F09%2F1497
n4:rokUplatneniVysledku
n16:2013
n4:svazekPeriodika
18
n4:tvurceVysledku
Vilhanová, B. Šot, P. Kuzma, Marek Václavík, J. Kačer, P. Pecháček, J.
n4:wos
000320770800038
s:issn
1420-3049
s:numberOfPages
25
n19:doi
10.3390/molecules18066804