This HTML5 document contains 43 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n17http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n14http://linked.opendata.cz/resource/domain/vavai/projekt/
n10http://linked.opendata.cz/resource/domain/vavai/subjekt/
n5http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61388971%3A_____%2F13%3A00425776%21RIV14-AV0-61388971/
n9http://linked.opendata.cz/ontology/domain/vavai/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n13http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n4http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n19http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n11http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n6http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n7http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61388971%3A_____%2F13%3A00425776%21RIV14-AV0-61388971
rdf:type
n9:Vysledek skos:Concept
dcterms:description
Two polysaccharide stationary phases have been newly suggested for application in hydrophilic interaction chromatography (HILIC). Both columns (amylose-silica, 250 x 4.6 mm, 5 m and cellulose-silica, 250 x 4.6 mm, 5 m) demonstrated a satisfactory retention of polar compounds. The influence of the mobile-phase composition (acetonitrile content, pH, salt concentration) on the retention was in agreement with the HILIC concept. The phases showed a very similar behavior, typical efficiency of about 50000 plates/m, cellulose retained test compounds somewhat more strongly. Under the experimental conditions, electrostatic (non-HILIC-type) interactions due to the dissociation of silanol groups on the silica surface did not influence the retention, noticeably. The applicability of polysaccharide stationary phases for the chromatography of polar compounds was proven by the separation of mixtures of sugars (fructose, glucose, saccharose, maltose, trehalose) or vitamins (nicotinamide, pyridoxine, riboflavin, thiamine, nicotinic acid, ascorbic acid) Two polysaccharide stationary phases have been newly suggested for application in hydrophilic interaction chromatography (HILIC). Both columns (amylose-silica, 250 x 4.6 mm, 5 m and cellulose-silica, 250 x 4.6 mm, 5 m) demonstrated a satisfactory retention of polar compounds. The influence of the mobile-phase composition (acetonitrile content, pH, salt concentration) on the retention was in agreement with the HILIC concept. The phases showed a very similar behavior, typical efficiency of about 50000 plates/m, cellulose retained test compounds somewhat more strongly. Under the experimental conditions, electrostatic (non-HILIC-type) interactions due to the dissociation of silanol groups on the silica surface did not influence the retention, noticeably. The applicability of polysaccharide stationary phases for the chromatography of polar compounds was proven by the separation of mixtures of sugars (fructose, glucose, saccharose, maltose, trehalose) or vitamins (nicotinamide, pyridoxine, riboflavin, thiamine, nicotinic acid, ascorbic acid)
dcterms:title
Underivatized amylose and cellulose as new stationary phases for hydrophilic interaction chromatography Underivatized amylose and cellulose as new stationary phases for hydrophilic interaction chromatography
skos:prefLabel
Underivatized amylose and cellulose as new stationary phases for hydrophilic interaction chromatography Underivatized amylose and cellulose as new stationary phases for hydrophilic interaction chromatography
skos:notation
RIV/61388971:_____/13:00425776!RIV14-AV0-61388971
n9:predkladatel
n10:ico%3A61388971
n3:aktivita
n12:S n12:P n12:I
n3:aktivity
I, P(ED2.1.00/03.0058), S
n3:cisloPeriodika
20
n3:dodaniDat
n7:2014
n3:domaciTvurceVysledku
n17:4316851
n3:druhVysledku
n11:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
112564
n3:idVysledku
RIV/61388971:_____/13:00425776
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Amylose; Cellulose; Hydrophilic interaction chromatography
n3:klicoveSlovo
n4:Amylose n4:Hydrophilic%20interaction%20chromatography n4:Cellulose
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[6F4D4FF82847]
n3:nazevZdroje
Journal of Separation Science
n3:obor
n6:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n14:ED2.1.00%2F03.0058
n3:rokUplatneniVysledku
n7:2013
n3:svazekPeriodika
36
n3:tvurceVysledku
Lemr, Karel Douša, M. Lehnert, P.
n3:wos
000325482500006
s:issn
1615-9306
s:numberOfPages
6
n13:doi
10.1002/jssc.201300577