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Statements

Subject Item
n2:RIV%2F61388971%3A_____%2F13%3A00392677%21RIV14-AV0-61388971
rdf:type
n6:Vysledek skos:Concept
dcterms:description
The reactions of the organoantimony(I) compound (L4Sb4)-Sb-1 (1) (where L-1 = [o-C6H4(CH=NC6H3(i-Pr)(2)-2,6)]) with diphenyldichalcogenides PhEEPh (E = S, Se, or Te) gave compounds (LSb)-Sb-1(EPh)(2) (E = S (2), Se (3), Te (4)) as the result of the oxidative addition of the antimony(I) atom across the chalcogen-chalcogen bond. The reaction of diphenyldichalcogenides PhEEPh with an in situ prepared organobismuth(I) compound (via reaction of the parent chloride (LBiCl2)-Bi-1 (5) with two equivalents of K[B(s-Bu)(3)H]) gave surprisingly diorganobismuth compounds (L2Bi)-Bi-1(EPh) (E = S (6), Se (7), Te (8)) as the major products along with only a trace amount of the intended compounds (LBi)-Bi-1(EPh)(2) (E = S (9), Se (10), Te (11)) The reactions of the organoantimony(I) compound (L4Sb4)-Sb-1 (1) (where L-1 = [o-C6H4(CH=NC6H3(i-Pr)(2)-2,6)]) with diphenyldichalcogenides PhEEPh (E = S, Se, or Te) gave compounds (LSb)-Sb-1(EPh)(2) (E = S (2), Se (3), Te (4)) as the result of the oxidative addition of the antimony(I) atom across the chalcogen-chalcogen bond. The reaction of diphenyldichalcogenides PhEEPh with an in situ prepared organobismuth(I) compound (via reaction of the parent chloride (LBiCl2)-Bi-1 (5) with two equivalents of K[B(s-Bu)(3)H]) gave surprisingly diorganobismuth compounds (L2Bi)-Bi-1(EPh) (E = S (6), Se (7), Te (8)) as the major products along with only a trace amount of the intended compounds (LBi)-Bi-1(EPh)(2) (E = S (9), Se (10), Te (11))
dcterms:title
Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds
skos:prefLabel
Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds
skos:notation
RIV/61388971:_____/13:00392677!RIV14-AV0-61388971
n6:predkladatel
n13:ico%3A61388971
n4:aktivita
n16:S n16:P n16:I
n4:aktivity
I, P(GAP207/10/0130), S
n4:cisloPeriodika
1
n4:dodaniDat
n8:2014
n4:domaciTvurceVysledku
n19:5854415
n4:druhVysledku
n17:J
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n14:predkladatel
n4:idSjednocenehoVysledku
95083
n4:idVysledku
RIV/61388971:_____/13:00392677
n4:jazykVysledku
n5:eng
n4:klicovaSlova
MAIN-GROUP ELEMENTS; BOND COVALENT RADII; CRYSTAL-STRUCTURES
n4:klicoveSlovo
n7:MAIN-GROUP%20ELEMENTS n7:CRYSTAL-STRUCTURES n7:BOND%20COVALENT%20RADII
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[21FCF29383EA]
n4:nazevZdroje
Organometallics
n4:obor
n18:CA
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
4
n4:projekt
n15:GAP207%2F10%2F0130
n4:rokUplatneniVysledku
n8:2013
n4:svazekPeriodika
32
n4:tvurceVysledku
Jambor, R. Šimon, Petr Růžička, A. Dostál, I.
n4:wos
000313606200028
s:issn
0276-7333
s:numberOfPages
10
n9:doi
10.1021/om3010383