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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F13%3A00391782%21RIV14-GA0-61388963
rdf:type
skos:Concept n15:Vysledek
rdfs:seeAlso
https://www.beilstein-journals.org/bjoc/single/articleFullText.htm?vt=f&publicId=1860-5397-9-43&tpn=1&bpn=singleVolume&vn=9
dcterms:description
Meta- or para-nitro-(pentafluorosulfonyl)benzenes underwent the Davis reaction with arylacetonitriles to provide the SF5-containing benzisoxazoles. Good yields were obtained with arylacetonitriles containing the electron-neutral or electron-donor group, while those with the electron-acceptor group were found to be unreactive. Reductions of the benzisoxazoles gave ortho-aminobenzophenones in high yields. Their synthetic utility was demonstrated by condensation reactions with carbonyl compounds or amines to provide SF5-containing quinolines and quinazolines, respectively. Meta- or para-nitro-(pentafluorosulfonyl)benzenes underwent the Davis reaction with arylacetonitriles to provide the SF5-containing benzisoxazoles. Good yields were obtained with arylacetonitriles containing the electron-neutral or electron-donor group, while those with the electron-acceptor group were found to be unreactive. Reductions of the benzisoxazoles gave ortho-aminobenzophenones in high yields. Their synthetic utility was demonstrated by condensation reactions with carbonyl compounds or amines to provide SF5-containing quinolines and quinazolines, respectively.
dcterms:title
Synthesis of SF5-containing benzisoxazoles, quinolines, and quinazolines by the Davis reaction of nitro-(pentafluorosulfanyl)benzenes Synthesis of SF5-containing benzisoxazoles, quinolines, and quinazolines by the Davis reaction of nitro-(pentafluorosulfanyl)benzenes
skos:prefLabel
Synthesis of SF5-containing benzisoxazoles, quinolines, and quinazolines by the Davis reaction of nitro-(pentafluorosulfanyl)benzenes Synthesis of SF5-containing benzisoxazoles, quinolines, and quinazolines by the Davis reaction of nitro-(pentafluorosulfanyl)benzenes
skos:notation
RIV/61388963:_____/13:00391782!RIV14-GA0-61388963
n15:predkladatel
n16:ico%3A61388963
n3:aktivita
n4:I n4:P
n3:aktivity
I, P(GAP207/12/0072)
n3:cisloPeriodika
Feb 21
n3:dodaniDat
n11:2014
n3:domaciTvurceVysledku
n9:7217544 n9:4912039
n3:druhVysledku
n20:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
109554
n3:idVysledku
RIV/61388963:_____/13:00391782
n3:jazykVysledku
n19:eng
n3:klicovaSlova
benzisoxazoles; pentafluorosulfanyl group; quinazolines; quinolines; sulfurpentafluorides
n3:klicoveSlovo
n5:benzisoxazoles n5:quinazolines n5:quinolines n5:pentafluorosulfanyl%20group n5:sulfurpentafluorides
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[F289FAB9F473]
n3:nazevZdroje
Beilstein Journal of Organic Chemistry
n3:obor
n12:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n18:GAP207%2F12%2F0072
n3:rokUplatneniVysledku
n11:2013
n3:svazekPeriodika
9
n3:tvurceVysledku
Beier, Petr Pastýříková, Tereza
n3:wos
000315411800001
s:issn
1860-5397
s:numberOfPages
6
n10:doi
10.3762/bjoc.9.43