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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F12%3A00380643%21RIV13-AV0-61388963
rdf:type
skos:Concept n15:Vysledek
dcterms:description
Pyrogallol[4]arene is a macrocycle with a concave surface and 12 peripheral hydroxyl groups that mediate its self-assembly to form hexamers of octahedral symmetry in the solid state, in solution, and in the gas phase. In this study, we show that solvent-free conditions for guest entrapment in these hexamers, using molten guest molecules as solvent and allowing the capsules to assemble during cooling, results in exceptionally kinetically stable encapsulation complexes that are not formed in the presence of solvent and are not thermodynamically stable. Pyrogallol[4]arene is a macrocycle with a concave surface and 12 peripheral hydroxyl groups that mediate its self-assembly to form hexamers of octahedral symmetry in the solid state, in solution, and in the gas phase. In this study, we show that solvent-free conditions for guest entrapment in these hexamers, using molten guest molecules as solvent and allowing the capsules to assemble during cooling, results in exceptionally kinetically stable encapsulation complexes that are not formed in the presence of solvent and are not thermodynamically stable.
dcterms:title
Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions
skos:prefLabel
Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions Molecular Encapsulation in Pyrogallolarene Hexamers Under Nonequilibrium Conditions
skos:notation
RIV/61388963:_____/12:00380643!RIV13-AV0-61388963
n15:predkladatel
n16:ico%3A61388963
n3:aktivita
n14:Z
n3:aktivity
Z(AV0Z40550506)
n3:cisloPeriodika
36
n3:dodaniDat
n8:2013
n3:domaciTvurceVysledku
n17:8579377
n3:druhVysledku
n19:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
151538
n3:idVysledku
RIV/61388963:_____/12:00380643
n3:jazykVysledku
n7:eng
n3:klicovaSlova
pyrogallol[4]arene; hexamer; encapsulation; guest exchange
n3:klicoveSlovo
n5:guest%20exchange n5:encapsulation n5:pyrogallol%5B4%5Darene n5:hexamer
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[BE224A9BBA8E]
n3:nazevZdroje
Journal of the American Chemical Society
n3:obor
n12:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n8:2012
n3:svazekPeriodika
134
n3:tvurceVysledku
Purse, B. W. Kvasnica, Miroslav Chapin, J. C.
n3:wos
000308574800058
n3:zamer
n10:AV0Z40550506
s:issn
0002-7863
s:numberOfPages
10
n6:doi
10.1021/ja305252t