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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F12%3A00379965%21RIV13-AV0-61388963
rdf:type
n6:Vysledek skos:Concept
dcterms:description
Addition of diethyl lithiodifluoromethylphosphonate to N-substituted imines provides N-substituted alpha,alpha-difluoro-beta-aminophosphonates. N-Alkyl, aryl, or Boc substituted aldimines give good to high yields in these reactions, while in ketimine series, only activated N-(2,2,2-trifluoro-1-phenylethylidene)aniline showed high reactivity. Addition of diethyl lithiodifluoromethylphosphonate to N-substituted imines provides N-substituted alpha,alpha-difluoro-beta-aminophosphonates. N-Alkyl, aryl, or Boc substituted aldimines give good to high yields in these reactions, while in ketimine series, only activated N-(2,2,2-trifluoro-1-phenylethylidene)aniline showed high reactivity.
dcterms:title
Synthesis of N-substituted a,a-difluoro-b-aminophosphonates by addition of diethyl lithiodifluoromethylphosphonate to imines Synthesis of N-substituted a,a-difluoro-b-aminophosphonates by addition of diethyl lithiodifluoromethylphosphonate to imines
skos:prefLabel
Synthesis of N-substituted a,a-difluoro-b-aminophosphonates by addition of diethyl lithiodifluoromethylphosphonate to imines Synthesis of N-substituted a,a-difluoro-b-aminophosphonates by addition of diethyl lithiodifluoromethylphosphonate to imines
skos:notation
RIV/61388963:_____/12:00379965!RIV13-AV0-61388963
n6:predkladatel
n13:ico%3A61388963
n3:aktivita
n19:P n19:I
n3:aktivity
I, P(GP203/08/P310)
n3:cisloPeriodika
Sep
n3:dodaniDat
n9:2013
n3:domaciTvurceVysledku
Cherkupally, Prabhakar n17:4912039
n3:druhVysledku
n5:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
172976
n3:idVysledku
RIV/61388963:_____/12:00379965
n3:jazykVysledku
n4:eng
n3:klicovaSlova
nucleophilic addition; difluorophosphonate; aminophosphonate; imines
n3:klicoveSlovo
n8:difluorophosphonate n8:nucleophilic%20addition n8:imines n8:aminophosphonate
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[AB62F138582A]
n3:nazevZdroje
Journal of Fluorine Chemistry
n3:obor
n10:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n18:GP203%2F08%2FP310
n3:rokUplatneniVysledku
n9:2012
n3:svazekPeriodika
141
n3:tvurceVysledku
Cherkupally, Prabhakar Beier, Petr
n3:wos
000308120100012
s:issn
0022-1139
s:numberOfPages
7
n7:doi
10.1016/j.jfluchem.2012.06.004