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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F12%3A00379964%21RIV13-AV0-61388963
rdf:type
n5:Vysledek skos:Concept
dcterms:description
Diethyl 2-nitro-(pentafluorosulfanyl)benzylphosphonates, available by the vicarious nucleophilic substitution reaction of meta- and para-nitro-(pentafluorosulfanyl)benzenes and diethyl chloromethylphosphonate, undergo Horner-Wadsworth-Emmons reaction with aldehydes in the presence of potassium hydroxide in acetonitrile at ambient temperature to give (E)-2-nitro-1-alkenyl-(pentafluorosulfanyl)benzenes in good yields and high stereoselectivities. Follow-up transformations of the primary products provided (E)-1-alkenyl-(pentafluorosulfanyl)benzenes and 2-(2-arylethyl)-(pentafluorosulfanyl)anilines. Diethyl 2-nitro-(pentafluorosulfanyl)benzylphosphonates, available by the vicarious nucleophilic substitution reaction of meta- and para-nitro-(pentafluorosulfanyl)benzenes and diethyl chloromethylphosphonate, undergo Horner-Wadsworth-Emmons reaction with aldehydes in the presence of potassium hydroxide in acetonitrile at ambient temperature to give (E)-2-nitro-1-alkenyl-(pentafluorosulfanyl)benzenes in good yields and high stereoselectivities. Follow-up transformations of the primary products provided (E)-1-alkenyl-(pentafluorosulfanyl)benzenes and 2-(2-arylethyl)-(pentafluorosulfanyl)anilines.
dcterms:title
Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction
skos:prefLabel
Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction
skos:notation
RIV/61388963:_____/12:00379964!RIV13-AV0-61388963
n5:predkladatel
n17:ico%3A61388963
n6:aktivita
n10:P n10:I
n6:aktivity
I, P(GAP207/12/0072)
n6:cisloPeriodika
25 Jul
n6:dodaniDat
n13:2013
n6:domaciTvurceVysledku
n7:4912039 Iakobson, George
n6:druhVysledku
n11:J
n6:duvernostUdaju
n15:S
n6:entitaPredkladatele
n16:predkladatel
n6:idSjednocenehoVysledku
139016
n6:idVysledku
RIV/61388963:_____/12:00379964
n6:jazykVysledku
n19:eng
n6:klicovaSlova
Horner-Wadsworth-Emmons reaction; pentafluorosulfanyl group; phosphonates; sulfurpentafluoride
n6:klicoveSlovo
n9:pentafluorosulfanyl%20group n9:sulfurpentafluoride n9:Horner-Wadsworth-Emmons%20reaction n9:phosphonates
n6:kodStatuVydavatele
DE - Spolková republika Německo
n6:kontrolniKodProRIV
[383B3682CCA0]
n6:nazevZdroje
Beilstein Journal of Organic Chemistry
n6:obor
n18:CC
n6:pocetDomacichTvurcuVysledku
2
n6:pocetTvurcuVysledku
2
n6:projekt
n14:GAP207%2F12%2F0072
n6:rokUplatneniVysledku
n13:2012
n6:svazekPeriodika
8
n6:tvurceVysledku
Iakobson, George Beier, Petr
n6:wos
000306830900001
s:issn
1860-5397
s:numberOfPages
6
n12:doi
10.3762/bjoc.8.131