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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F12%3A00377716%21RIV13-AV0-61388963
rdf:type
n10:Vysledek skos:Concept
dcterms:description
Modified nucleoside mono- and triphosphates bearing bipyridine or terpyridine ligands attached via acetylene linker were prepared by single-step aqueous-phase Sonogashira cross-coupling of 7-iodo-7-deaza-dAMP or -dATP, and 5-iodo-dCMP or -dCTP with the corresponding bipyridine- or terpyridine-linked acetylenes. The modified dNTPs were successfully incorporated into the oligonucleotides by primer extension experiment (PEX) using different DNA polymerases and the PEX products were used for post-synthetic complexation with Fe2+. Modified nucleoside mono- and triphosphates bearing bipyridine or terpyridine ligands attached via acetylene linker were prepared by single-step aqueous-phase Sonogashira cross-coupling of 7-iodo-7-deaza-dAMP or -dATP, and 5-iodo-dCMP or -dCTP with the corresponding bipyridine- or terpyridine-linked acetylenes. The modified dNTPs were successfully incorporated into the oligonucleotides by primer extension experiment (PEX) using different DNA polymerases and the PEX products were used for post-synthetic complexation with Fe2+.
dcterms:title
Synthesis of nucleoside mono- and triphosphates bearing oligopyridine ligands, their incorporation into DNA and complexation with transition metals Synthesis of nucleoside mono- and triphosphates bearing oligopyridine ligands, their incorporation into DNA and complexation with transition metals
skos:prefLabel
Synthesis of nucleoside mono- and triphosphates bearing oligopyridine ligands, their incorporation into DNA and complexation with transition metals Synthesis of nucleoside mono- and triphosphates bearing oligopyridine ligands, their incorporation into DNA and complexation with transition metals
skos:notation
RIV/61388963:_____/12:00377716!RIV13-AV0-61388963
n10:predkladatel
n14:ico%3A61388963
n3:aktivita
n4:Z n4:P
n3:aktivity
P(GA203/09/0317), P(LC512), Z(AV0Z40550506)
n3:cisloPeriodika
1
n3:dodaniDat
n11:2013
n3:domaciTvurceVysledku
n15:1840584 n15:6659160 n15:3603652
n3:druhVysledku
n17:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
172977
n3:idVysledku
RIV/61388963:_____/12:00377716
n3:jazykVysledku
n7:eng
n3:klicovaSlova
nucleotides; terpyridine; DNA
n3:klicoveSlovo
n13:DNA n13:nucleotides n13:terpyridine
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[BDAA358B221E]
n3:nazevZdroje
Organic & Biomolecular Chemistry
n3:obor
n19:CC
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n16:GA203%2F09%2F0317 n16:LC512
n3:rokUplatneniVysledku
n11:2012
n3:svazekPeriodika
10
n3:tvurceVysledku
Kalachová, Lubica Hocek, Michal Pohl, Radek
n3:wos
000297589900009
n3:zamer
n8:AV0Z40550506
s:issn
1477-0520
s:numberOfPages
7
n20:doi
10.1039/c1ob06359f