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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F12%3A00376577%21RIV13-AV0-61388963
rdf:type
n16:Vysledek skos:Concept
dcterms:description
An efficient methodology for the synthesis of S-substituted derivatives of phosphonohomocysteine has been developed. It starts from the corresponding thiols and is based on a synthetic sequence consisting of (i) the Kabachnik-Fields reaction, (ii) the transesterification of the diphenylphosphoryl moiety and (iii) the acidic deprotection of the phosphoryl and amino groups. The proposed synthetic procedures describing syntheses of phosphonohomocysteine precursors with di-tert-butylphosphoryl and tert-butyloxycarbonylamino groups could be useful for the preparation of novel S-substituted phosphonohomocysteine derivatives. An efficient methodology for the synthesis of S-substituted derivatives of phosphonohomocysteine has been developed. It starts from the corresponding thiols and is based on a synthetic sequence consisting of (i) the Kabachnik-Fields reaction, (ii) the transesterification of the diphenylphosphoryl moiety and (iii) the acidic deprotection of the phosphoryl and amino groups. The proposed synthetic procedures describing syntheses of phosphonohomocysteine precursors with di-tert-butylphosphoryl and tert-butyloxycarbonylamino groups could be useful for the preparation of novel S-substituted phosphonohomocysteine derivatives.
dcterms:title
The synthesis of phosphonic acids derived from homocysteine via transesterification reactions The synthesis of phosphonic acids derived from homocysteine via transesterification reactions
skos:prefLabel
The synthesis of phosphonic acids derived from homocysteine via transesterification reactions The synthesis of phosphonic acids derived from homocysteine via transesterification reactions
skos:notation
RIV/61388963:_____/12:00376577!RIV13-AV0-61388963
n16:predkladatel
n18:ico%3A61388963
n4:aktivita
n11:Z n11:P
n4:aktivity
P(GA203/09/1919), P(GAP207/10/1277), Z(AV0Z40550506)
n4:cisloPeriodika
4
n4:dodaniDat
n12:2013
n4:domaciTvurceVysledku
n5:3046486 n5:1606778 n5:8977178 n5:6236219
n4:druhVysledku
n15:J
n4:duvernostUdaju
n10:S
n4:entitaPredkladatele
n19:predkladatel
n4:idSjednocenehoVysledku
172980
n4:idVysledku
RIV/61388963:_____/12:00376577
n4:jazykVysledku
n14:eng
n4:klicovaSlova
phosphonohomocysteine; aminophosphonic acids
n4:klicoveSlovo
n8:phosphonohomocysteine n8:aminophosphonic%20acids
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[D357CCED357A]
n4:nazevZdroje
ARKIVOC
n4:obor
n17:CC
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
4
n4:projekt
n7:GAP207%2F10%2F1277 n7:GA203%2F09%2F1919
n4:rokUplatneniVysledku
n12:2012
n4:tvurceVysledku
Pícha, Jan Fiedler, Pavel Buděšínský, Miloš Jiráček, Jiří
n4:wos
000308692300008
n4:zamer
n6:AV0Z40550506
s:issn
1551-7004
s:numberOfPages
20