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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F11%3A00369763%21RIV12-AV0-61388963
rdf:type
n12:Vysledek skos:Concept
dcterms:description
Tetramethylcyclobutadiene–AlCl3 complex reacted with bisalkynes possessing phenylene and biphenylene spacer giving rise to mono- and bis-Dewar benzenes. The rearrangement of the bis-Dewar benzene derivatives under thermal conditions (150 °C) yielded the corresponding linear ter- and quaterphenyl compounds possessing substituted terminal benzene rings. A mixture of an alkynylbiphenyl and a terphenyl was also obtained by the reaction of tetramethylzirconacyclopentadiene with bisalkynylbenzene in 13% combined yield. Tetramethylcyclobutadiene–AlCl3 complex reacted with bisalkynes possessing phenylene and biphenylene spacer giving rise to mono- and bis-Dewar benzenes. The rearrangement of the bis-Dewar benzene derivatives under thermal conditions (150 °C) yielded the corresponding linear ter- and quaterphenyl compounds possessing substituted terminal benzene rings. A mixture of an alkynylbiphenyl and a terphenyl was also obtained by the reaction of tetramethylzirconacyclopentadiene with bisalkynylbenzene in 13% combined yield.
dcterms:title
Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes
skos:prefLabel
Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes
skos:notation
RIV/61388963:_____/11:00369763!RIV12-AV0-61388963
n12:predkladatel
n18:ico%3A61388963
n5:aktivita
n10:Z n10:P
n5:aktivity
P(IAA401110805), P(LC06070), Z(AV0Z40550506), Z(MSM0021620857)
n5:cisloPeriodika
3
n5:dodaniDat
n13:2012
n5:domaciTvurceVysledku
n19:4268180
n5:druhVysledku
n20:J
n5:duvernostUdaju
n9:S
n5:entitaPredkladatele
n6:predkladatel
n5:idSjednocenehoVysledku
233919
n5:idVysledku
RIV/61388963:_____/11:00369763
n5:jazykVysledku
n17:eng
n5:klicovaSlova
dewar benzene; alkynes; cyclobutadiene; polycycles; metallacycles
n5:klicoveSlovo
n11:metallacycles n11:cyclobutadiene n11:polycycles n11:alkynes n11:dewar%20benzene
n5:kodStatuVydavatele
DE - Spolková republika Německo
n5:kontrolniKodProRIV
[09FC58708D40]
n5:nazevZdroje
Synlett
n5:obor
n16:CC
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
3
n5:projekt
n7:IAA401110805 n7:LC06070
n5:rokUplatneniVysledku
n13:2011
n5:svazekPeriodika
-
n5:tvurceVysledku
Janková, Š. Kotora, Martin Hybelbauerová, S.
n5:wos
000286922800023
n5:zamer
n15:AV0Z40550506 n15:MSM0021620857
s:issn
0936-5214
s:numberOfPages
3
n14:doi
10.1055/s-0030-1259321