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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F11%3A00369758%21RIV12-AV0-61388963
rdf:type
n10:Vysledek skos:Concept
dcterms:description
Four bis(tetrahydroisoquinoline) N,N-dioxides were used as catalysts for the epoxide ring opening with tetrachlorosilane under various conditions. A strong solvent effect on asymmetric induction was observed for each of the used catalysts. The highest achieved asymmetric induction for the opening of meso-stilbene oxide was 69% ee. Regarding the cycloalkene oxides, 56% ee was obtained in the reaction with cyclooctene oxide. Four bis(tetrahydroisoquinoline) N,N-dioxides were used as catalysts for the epoxide ring opening with tetrachlorosilane under various conditions. A strong solvent effect on asymmetric induction was observed for each of the used catalysts. The highest achieved asymmetric induction for the opening of meso-stilbene oxide was 69% ee. Regarding the cycloalkene oxides, 56% ee was obtained in the reaction with cyclooctene oxide.
dcterms:title
Enantioselective Epoxide Ring Opening Catalyzed by Bis(tetrahydroisoquinoline) N,N’-Dioxides Enantioselective Epoxide Ring Opening Catalyzed by Bis(tetrahydroisoquinoline) N,N’-Dioxides
skos:prefLabel
Enantioselective Epoxide Ring Opening Catalyzed by Bis(tetrahydroisoquinoline) N,N’-Dioxides Enantioselective Epoxide Ring Opening Catalyzed by Bis(tetrahydroisoquinoline) N,N’-Dioxides
skos:notation
RIV/61388963:_____/11:00369758!RIV12-AV0-61388963
n10:predkladatel
n15:ico%3A61388963
n3:aktivita
n17:Z n17:S n17:P
n3:aktivity
P(GAP207/11/0587), P(LC06070), S, Z(AV0Z40550506), Z(MSM0021620857)
n3:cisloPeriodika
5
n3:dodaniDat
n8:2012
n3:domaciTvurceVysledku
n11:4268180
n3:druhVysledku
n4:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
197431
n3:idVysledku
RIV/61388963:_____/11:00369758
n3:jazykVysledku
n18:eng
n3:klicovaSlova
asymmetric catalysis; silanes; N ligands; enantioselectivity
n3:klicoveSlovo
n6:enantioselectivity n6:asymmetric%20catalysis n6:silanes n6:N%20ligands
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[96ACAE1EB995]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communications
n3:obor
n20:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n5:LC06070 n5:GAP207%2F11%2F0587
n3:rokUplatneniVysledku
n8:2011
n3:svazekPeriodika
76
n3:tvurceVysledku
Kadlčíková, A. Kotora, Martin Vlašná, K.
n3:wos
000290280100006
n3:zamer
n14:AV0Z40550506 n14:MSM0021620857
s:issn
0010-0765
s:numberOfPages
8
n16:doi
10.1135/cccc2011024