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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F11%3A00363413%21RIV12-AV0-61388963
rdf:type
n7:Vysledek skos:Concept
dcterms:description
From optically pure [6]helicene-like alcohol four phosphites were prepared, which were applied to the asymmetric hydroformylation and the asymmetric allylic amination exhibiting high enantioselectivity (up to 94% ee). This study represents the first use of helicene-like ligands in asymmetric reactions. From optically pure [6]helicene-like alcohol four phosphites were prepared, which were applied to the asymmetric hydroformylation and the asymmetric allylic amination exhibiting high enantioselectivity (up to 94% ee). This study represents the first use of helicene-like ligands in asymmetric reactions.
dcterms:title
Helicene-Based Phosphite Ligands in Asymmetric Transition-Metal Catalysis: Exploring Rh-Catalyzed Hydroformylation and Ir-Catalyzed Allylic Amination Helicene-Based Phosphite Ligands in Asymmetric Transition-Metal Catalysis: Exploring Rh-Catalyzed Hydroformylation and Ir-Catalyzed Allylic Amination
skos:prefLabel
Helicene-Based Phosphite Ligands in Asymmetric Transition-Metal Catalysis: Exploring Rh-Catalyzed Hydroformylation and Ir-Catalyzed Allylic Amination Helicene-Based Phosphite Ligands in Asymmetric Transition-Metal Catalysis: Exploring Rh-Catalyzed Hydroformylation and Ir-Catalyzed Allylic Amination
skos:notation
RIV/61388963:_____/11:00363413!RIV12-AV0-61388963
n7:predkladatel
n8:ico%3A61388963
n3:aktivita
n5:Z n5:P
n3:aktivity
P(GA203/09/1766), P(LC512), Z(AV0Z40550506)
n3:cisloPeriodika
20/21
n3:dodaniDat
n14:2012
n3:domaciTvurceVysledku
n6:8624526 n6:4128575 n6:5761794 n6:5011906 n6:7478593
n3:druhVysledku
n12:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
201857
n3:idVysledku
RIV/61388963:_____/11:00363413
n3:jazykVysledku
n11:eng
n3:klicovaSlova
asymmetric catalysis; helical structures; P ligands; hydroformylation; amination
n3:klicoveSlovo
n4:hydroformylation n4:P%20ligands n4:asymmetric%20catalysis n4:amination n4:helical%20structures
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[18C8D2B1C0D3]
n3:nazevZdroje
European Journal of Organic Chemistry
n3:obor
n19:CC
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
8
n3:projekt
n18:GA203%2F09%2F1766 n18:LC512
n3:rokUplatneniVysledku
n14:2011
n3:svazekPeriodika
-
n3:tvurceVysledku
Eilbracht, P. Bondzic, B. P. Šaman, David Chercheja, S. Krausová, Zuzana Stará, Irena G. Sehnal, Petr Starý, Ivo
n3:wos
000293440900032
n3:zamer
n15:AV0Z40550506
s:issn
1434-193X
s:numberOfPages
9
n16:doi
10.1002/ejoc.201100259