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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F11%3A00363302%21RIV12-AV0-61388963
rdf:type
n13:Vysledek skos:Concept
dcterms:description
A dicationic [6]helicene congener captured on the racemization pathway in its saddle-shaped geometry is introduced. The dynamic aspects established by experiment and supported by detailed DFT-D calculations are presented visually in the form of a movie (electronic table-of-contents and electronic supplementary information). The title [6]saddlequat was found to be an isolable chiral species on the entirely chiral enantiomerization pathway of a [6]helquat that is discussed as an example of Mislow’s rubber glove’’ molecule. A dicationic [6]helicene congener captured on the racemization pathway in its saddle-shaped geometry is introduced. The dynamic aspects established by experiment and supported by detailed DFT-D calculations are presented visually in the form of a movie (electronic table-of-contents and electronic supplementary information). The title [6]saddlequat was found to be an isolable chiral species on the entirely chiral enantiomerization pathway of a [6]helquat that is discussed as an example of Mislow’s rubber glove’’ molecule.
dcterms:title
[6]Saddlequat: a [6]helquat captured on its racemization pathway [6]Saddlequat: a [6]helquat captured on its racemization pathway
skos:prefLabel
[6]Saddlequat: a [6]helquat captured on its racemization pathway [6]Saddlequat: a [6]helquat captured on its racemization pathway
skos:notation
RIV/61388963:_____/11:00363302!RIV12-AV0-61388963
n13:predkladatel
n20:ico%3A61388963
n3:aktivita
n11:Z n11:S n11:P
n3:aktivity
P(GA203/08/1428), P(GA203/09/1614), P(GAP207/10/2391), P(GP203/09/P485), S, Z(AV0Z40550506), Z(MSM0021620857)
n3:cisloPeriodika
12
n3:dodaniDat
n10:2012
n3:domaciTvurceVysledku
n4:7844816 n4:9379789 n4:3603652 n4:7710070 n4:3169138 Adriaenssens, Louis n4:7478593 n4:3804771 n4:4636406
n3:druhVysledku
n5:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
244241
n3:idVysledku
RIV/61388963:_____/11:00363302
n3:jazykVysledku
n16:eng
n3:klicovaSlova
dynamic stereochemistry; kinetic [2+2+2] cycloaddition; DFT and spectroscopy
n3:klicoveSlovo
n7:kinetic%20%5B2%2B2%2B2%5D%20cycloaddition n7:dynamic%20stereochemistry n7:DFT%20and%20spectroscopy
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[5F7B733B74E7]
n3:nazevZdroje
Chemical Science
n3:obor
n12:CC
n3:pocetDomacichTvurcuVysledku
9
n3:pocetTvurcuVysledku
14
n3:projekt
n9:GP203%2F09%2FP485 n9:GAP207%2F10%2F2391 n9:GA203%2F08%2F1428 n9:GA203%2F09%2F1614
n3:rokUplatneniVysledku
n10:2011
n3:svazekPeriodika
2
n3:tvurceVysledku
Escudero-Adán, E. C. Novotná, P. Pohl, Radek Sázelová, Petra Šaman, David Koval, Dušan Urbanová, M. Severa, Lukáš Teplý, Filip Vávra, Jan Císařová, I. Adriaenssens, Louis Kašička, Václav Belmonte, M. M.
n3:wos
000296745500005
n3:zamer
n15:AV0Z40550506 n15:MSM0021620857
s:issn
2041-6520
s:numberOfPages
8
n17:doi
10.1039/c1sc00468a