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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F11%3A00360880%21RIV12-AV0-61388963
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields. Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields.
dcterms:title
1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds
skos:prefLabel
1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds
skos:notation
RIV/61388963:_____/11:00360880!RIV12-AV0-61388963
n14:predkladatel
n20:ico%3A61388963
n4:aktivita
n7:P n7:Z
n4:aktivity
P(GP203/08/P310), Z(AV0Z40550506)
n4:cisloPeriodika
5
n4:dodaniDat
n5:2012
n4:domaciTvurceVysledku
n11:4912039 n11:6582796
n4:druhVysledku
n19:J
n4:duvernostUdaju
n10:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
243935
n4:idVysledku
RIV/61388963:_____/11:00360880
n4:jazykVysledku
n17:eng
n4:klicovaSlova
1,4-addition; phosphonates; fluorine
n4:klicoveSlovo
n6:4-addition n6:fluorine n6:phosphonates n6:1
n4:kodStatuVydavatele
CH - Švýcarská konfederace
n4:kontrolniKodProRIV
[6E9D4C309617]
n4:nazevZdroje
Journal of Fluorine Chemistry
n4:obor
n13:CC
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
2
n4:projekt
n12:GP203%2F08%2FP310
n4:rokUplatneniVysledku
n5:2011
n4:svazekPeriodika
132
n4:tvurceVysledku
Beier, Petr Opekar, Stanislav
n4:wos
000291286000009
n4:zamer
n16:AV0Z40550506
s:issn
0022-1139
s:numberOfPages
4
n18:doi
10.1016/j.jfluchem.2011.03.011