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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F10%3A00350078%21RIV11-MSM-61388963
rdf:type
n4:Vysledek skos:Concept
dcterms:description
A modular and efficient synthesis of 5-(hetero)arylfuran C-2'-deoxyribonucleosides was developed. Friedel–Crafts C-glycosidation of 2-bromofuran with toluoyl-protected methyl 2'-deoxyribofuranoside in the presence of BF3Et2O gave 5- bromofuran C-nucleosides, which were used as key intermediates for Stille or Suzuki coupling with (hetero)arylstannanes or boronic acids to afford a series of 5-(hetero)arylfuran C-nucleosides. A modular and efficient synthesis of 5-(hetero)arylfuran C-2'-deoxyribonucleosides was developed. Friedel–Crafts C-glycosidation of 2-bromofuran with toluoyl-protected methyl 2'-deoxyribofuranoside in the presence of BF3Et2O gave 5- bromofuran C-nucleosides, which were used as key intermediates for Stille or Suzuki coupling with (hetero)arylstannanes or boronic acids to afford a series of 5-(hetero)arylfuran C-nucleosides.
dcterms:title
Modular Synthesis of 5-Substituted Furan-2-yl C-2'-Deoxyribonucleosides and Biaryl Covalent Base-pair Analogues Modular Synthesis of 5-Substituted Furan-2-yl C-2'-Deoxyribonucleosides and Biaryl Covalent Base-pair Analogues
skos:prefLabel
Modular Synthesis of 5-Substituted Furan-2-yl C-2'-Deoxyribonucleosides and Biaryl Covalent Base-pair Analogues Modular Synthesis of 5-Substituted Furan-2-yl C-2'-Deoxyribonucleosides and Biaryl Covalent Base-pair Analogues
skos:notation
RIV/61388963:_____/10:00350078!RIV11-MSM-61388963
n3:aktivita
n11:Z n11:P
n3:aktivity
P(IAA400550902), P(LC512), Z(AV0Z40550506)
n3:cisloPeriodika
28
n3:dodaniDat
n6:2011
n3:domaciTvurceVysledku
n5:3357457 n5:7345828 n5:6659160 n5:3839664
n3:druhVysledku
n18:J
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
272311
n3:idVysledku
RIV/61388963:_____/10:00350078
n3:jazykVysledku
n17:eng
n3:klicovaSlova
C-nucleosides; furans; C-glycosidation; cross-coupling reactions
n3:klicoveSlovo
n16:furans n16:C-nucleosides n16:cross-coupling%20reactions n16:C-glycosidation
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[63DDC7219DAF]
n3:nazevZdroje
European Journal of Organic Chemistry
n3:obor
n13:CC
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n12:LC512 n12:IAA400550902
n3:rokUplatneniVysledku
n6:2010
n3:svazekPeriodika
-
n3:tvurceVysledku
Hocek, Michal Klepetářová, Blanka Bárta, Jan Slavětínská, Lenka
n3:wos
000283387900013
n3:zamer
n10:AV0Z40550506
s:issn
1434-193X
s:numberOfPages
12