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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F09%3A00331253%21RIV10-MSM-61388963
rdf:type
n12:Vysledek skos:Concept
dcterms:description
Experimental data were interpreted based on a very good agreement between theoretical and experimental results. The most intense band in the spectra centered at 2205 cm-1 was assigned to monocarbonyl complexes formed on Mg2+ cations located in the six-member ring separating two adjacent FER cages (P6 site); it is concluded that Mg2+ cations exchange preferably into this site. An unusually high site-specificity of CO observed for CO complexes formed in Mg-FER can be exploited in the investigation of preferable exchange sites of Mg2+ in zeolites and in the investigation of the localization of Al pairs in zeolites. Experimental data were interpreted based on a very good agreement between theoretical and experimental results. The most intense band in the spectra centered at 2205 cm-1 was assigned to monocarbonyl complexes formed on Mg2+ cations located in the six-member ring separating two adjacent FER cages (P6 site); it is concluded that Mg2+ cations exchange preferably into this site. An unusually high site-specificity of CO observed for CO complexes formed in Mg-FER can be exploited in the investigation of preferable exchange sites of Mg2+ in zeolites and in the investigation of the localization of Al pairs in zeolites.
dcterms:title
Localization and Coordination of Mg2+ Cations in Ferrierite: Combined FTIR Spectroscopic and Computation Investigation of CO Adsorption Complexes Localization and Coordination of Mg2+ Cations in Ferrierite: Combined FTIR Spectroscopic and Computation Investigation of CO Adsorption Complexes
skos:prefLabel
Localization and Coordination of Mg2+ Cations in Ferrierite: Combined FTIR Spectroscopic and Computation Investigation of CO Adsorption Complexes Localization and Coordination of Mg2+ Cations in Ferrierite: Combined FTIR Spectroscopic and Computation Investigation of CO Adsorption Complexes
skos:notation
RIV/61388963:_____/09:00331253!RIV10-MSM-61388963
n3:aktivita
n5:P n5:Z
n3:aktivity
P(GA203/06/0324), P(GA203/09/0143), P(LC512), Z(AV0Z40550506), Z(MSM0021620857), Z(MSM6383917201)
n3:cisloPeriodika
25
n3:dodaniDat
n14:2010
n3:domaciTvurceVysledku
n18:1747681
n3:druhVysledku
n17:J
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
323994
n3:idVysledku
RIV/61388963:_____/09:00331253
n3:jazykVysledku
n16:eng
n3:klicovaSlova
FTIR; DFT; Mg-FER
n3:klicoveSlovo
n8:DFT n8:FTIR n8:Mg-FER
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[ECBDC3D4A9D6]
n3:nazevZdroje
Journal of Physical Chemistry C
n3:obor
n13:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:projekt
n15:LC512 n15:GA203%2F09%2F0143 n15:GA203%2F06%2F0324
n3:rokUplatneniVysledku
n14:2009
n3:svazekPeriodika
113
n3:tvurceVysledku
Hadjiivanov, K. Bulánek, R. Nachtigall, Petr Voleská, I. Ivanova, E.
n3:wos
000267205700032
n3:zamer
n4:MSM0021620857 n4:AV0Z40550506 n4:MSM6383917201
s:issn
1932-7447
s:numberOfPages
11