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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F09%3A00328738%21RIV10-MSM-61388963
rdf:type
skos:Concept n15:Vysledek
dcterms:description
An interesting dichotomy in regioselectivity and mechanism of direct C-H arylation of 1,3-dimethyluracil was observed. Its Pd-catalyzed reactions with diverse aryl halides in absence of CuI lead preferentially to 5-aryluracils, while the reactions in presence of CuI give 6-aryl derivatives as major products. An interesting dichotomy in regioselectivity and mechanism of direct C-H arylation of 1,3-dimethyluracil was observed. Its Pd-catalyzed reactions with diverse aryl halides in absence of CuI lead preferentially to 5-aryluracils, while the reactions in presence of CuI give 6-aryl derivatives as major products.
dcterms:title
Switching the regioselectivity of direct C-H arylation of 1,3-dimethyluracil Switching the regioselectivity of direct C-H arylation of 1,3-dimethyluracil
skos:prefLabel
Switching the regioselectivity of direct C-H arylation of 1,3-dimethyluracil Switching the regioselectivity of direct C-H arylation of 1,3-dimethyluracil
skos:notation
RIV/61388963:_____/09:00328738!RIV10-MSM-61388963
n4:aktivita
n12:P n12:Z
n4:aktivity
P(LC06077), Z(AV0Z40550506)
n4:cisloPeriodika
22
n4:dodaniDat
n7:2010
n4:domaciTvurceVysledku
n8:6659160 Čerňová, Miroslava n8:3603652
n4:druhVysledku
n13:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n18:predkladatel
n4:idSjednocenehoVysledku
344949
n4:idVysledku
RIV/61388963:_____/09:00328738
n4:jazykVysledku
n6:eng
n4:klicovaSlova
pyrimidines; C-H arylation; palladium
n4:klicoveSlovo
n5:C-H%20arylation n5:pyrimidines n5:palladium
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[339F0420E1A4]
n4:nazevZdroje
European Journal of Organic Chemistry
n4:obor
n16:CC
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
3
n4:projekt
n11:LC06077
n4:rokUplatneniVysledku
n7:2009
n4:svazekPeriodika
-
n4:tvurceVysledku
Čerňová, Miroslava Hocek, Michal Pohl, Radek
n4:wos
000268659900007
n4:zamer
n10:AV0Z40550506
s:issn
1434-193X
s:numberOfPages
4