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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F08%3A00314403%21RIV09-AV0-61388963
rdf:type
skos:Concept n11:Vysledek
dcterms:description
A tetrapodal pentadentate nitrogen ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) is used for the synthesis of the azido-iron(III) complex [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionization affords the dication [(1)Fe(N3)]2+ as well as the dicationic nitrido-iron species [(1)FeN]2+. A tetrapodal pentadentate nitrogen ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) is used for the synthesis of the azido-iron(III) complex [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionization affords the dication [(1)Fe(N3)]2+ as well as the dicationic nitrido-iron species [(1)FeN]2+. Tetrapodální pentadentální dusíkatý ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) je používán pro syntézu komplexu azidu kovu(III) [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionizace poskytuje dikationt [(1)Fe(N3)]2+ spolu s dikationickými sloučeninami nitridů kovu [(1)FeN]2+.
dcterms:title
Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins Aktivace C-H a N-H vazeb v plynné fázi vysoce valentním dikationtem nitridu kovu a {NH}-přenos k aktivaci olefinů
skos:prefLabel
Aktivace C-H a N-H vazeb v plynné fázi vysoce valentním dikationtem nitridu kovu a {NH}-přenos k aktivaci olefinů Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins
skos:notation
RIV/61388963:_____/08:00314403!RIV09-AV0-61388963
n3:aktivita
n9:P n9:Z
n3:aktivity
P(KJB400550704), Z(AV0Z40550506)
n3:cisloPeriodika
13
n3:dodaniDat
n8:2009
n3:domaciTvurceVysledku
Schröder, Detlef
n3:druhVysledku
n10:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
368957
n3:idVysledku
RIV/61388963:_____/08:00314403
n3:jazykVysledku
n16:eng
n3:klicovaSlova
azides; bond activation; dications; iron; mass spectrometry; metal nitrenes
n3:klicoveSlovo
n4:mass%20spectrometry n4:metal%20nitrenes n4:dications n4:azides n4:iron n4:bond%20activation
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[A8C481A903F5]
n3:nazevZdroje
Journal of the American Chemical Society
n3:obor
n5:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
9
n3:projekt
n17:KJB400550704
n3:rokUplatneniVysledku
n8:2008
n3:svazekPeriodika
130
n3:tvurceVysledku
Neugebauer, J. Schwarz, H. Haryono, M. Grohmann, A. Reiher, M. Schröder, Detlef Schlangen, M. Heinemann, F. W. López, J. P.
n3:wos
000254549000028
n3:zamer
n15:AV0Z40550506
s:issn
0002-7863
s:numberOfPages
10