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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F08%3A00306339%21RIV08-AV0-61388963
rdf:type
skos:Concept n17:Vysledek
dcterms:description
A combination of variable temperature FTIR spectroscopy with calculations performed at the periodic DFT level was used in the investigation of CO adsorption on zeolites Na-ZSM-5 and K-ZSM-5. On the basis of a very good agreement between experimental and calculated frequencies and adsorption enthalpies it is concluded that CO can form a linearly bridged adsorption complexes on the dual cation sites. Kombinace experimentální VTIR spektroskopie s výpočty provedenými na úrovni peroidického DFT modelu byla použita ke studiu adsorpce CO na zeolitech Na-ZSM-5 a K-ZSM-5. Na základě velmi dobré shody experimentálních a vypočtených vibračních frekvencí a adsorpčních enthalpií bylo potvrzeno, že molekly CO mohou vytvářet karbonyly mezi dvěma kationty v tzv. duálních kationtových pozicích. A combination of variable temperature FTIR spectroscopy with calculations performed at the periodic DFT level was used in the investigation of CO adsorption on zeolites Na-ZSM-5 and K-ZSM-5. On the basis of a very good agreement between experimental and calculated frequencies and adsorption enthalpies it is concluded that CO can form a linearly bridged adsorption complexes on the dual cation sites.
dcterms:title
Computational and fourier transform infrared spectroscopic studies on carbon monoxide adsorption on the zeolites Na-ZSM-5 and K-ZSM-5: Evidence of dual-cation sites Computational and fourier transform infrared spectroscopic studies on carbon monoxide adsorption on the zeolites Na-ZSM-5 and K-ZSM-5: Evidence of dual-cation sites Teoretická a FTIR studie adsorpce CO v zeolitech Na-ZSM-5 a K-ZSM-5: evidence duálních kationtových pozic
skos:prefLabel
Teoretická a FTIR studie adsorpce CO v zeolitech Na-ZSM-5 a K-ZSM-5: evidence duálních kationtových pozic Computational and fourier transform infrared spectroscopic studies on carbon monoxide adsorption on the zeolites Na-ZSM-5 and K-ZSM-5: Evidence of dual-cation sites Computational and fourier transform infrared spectroscopic studies on carbon monoxide adsorption on the zeolites Na-ZSM-5 and K-ZSM-5: Evidence of dual-cation sites
skos:notation
RIV/61388963:_____/08:00306339!RIV08-AV0-61388963
n3:strany
4658;4666
n3:aktivita
n15:Z n15:P
n3:aktivity
P(GA203/06/0324), P(LC512), Z(AV0Z40550506)
n3:cisloPeriodika
12
n3:dodaniDat
n7:2008
n3:domaciTvurceVysledku
Pulido, Maria Angeles n14:1747681
n3:druhVysledku
n16:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
360860
n3:idVysledku
RIV/61388963:_____/08:00306339
n3:jazykVysledku
n18:eng
n3:klicovaSlova
zeolit; adsorpce; FTIR
n3:klicoveSlovo
n9:FTIR n9:adsorpce n9:zeolit
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[2C3D99CACC51]
n3:nazevZdroje
Journal of Physical Chemistry C
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
7
n3:projekt
n11:GA203%2F06%2F0324 n11:LC512
n3:rokUplatneniVysledku
n7:2008
n3:svazekPeriodika
112
n3:tvurceVysledku
Bibiloni, G. F. Bulánek, R. Frolich, K. Nachtigall, Petr Delgado, M. R. Areán, C. O. Pulido, Maria Angeles
n3:zamer
n4:AV0Z40550506
s:issn
1932-7447
s:numberOfPages
9