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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F07%3A00090323%21RIV08-AV0-61388963
rdf:type
skos:Concept n15:Vysledek
dcterms:description
V článku je ukázán vliv hydratace na tautomerní rovnováhu bází nukleových kyselin a prostorové uspořádání párů bází. Je ukázán význam specifických interakcí bází s molekulami rozpouštědla. We demonstrate the strong influence of a solvent on the tautomeric equilibrium between the tautomers of bases and on the spatial arrangement of the bases in a base pair. The results provide clear evidence that the prevalence of either the stacked or hydrogen-bonded structures of the base pairs in the solvent is not determined only by its bulk properties, but rather by specific hydrophilic interactions of the base pair with a small number of solvent molecules. We demonstrate the strong influence of a solvent on the tautomeric equilibrium between the tautomers of bases and on the spatial arrangement of the bases in a base pair. The results provide clear evidence that the prevalence of either the stacked or hydrogen-bonded structures of the base pairs in the solvent is not determined only by its bulk properties, but rather by specific hydrophilic interactions of the base pair with a small number of solvent molecules.
dcterms:title
Hydratace a stabilita bází nukleových kyselin a jejich párů Hydration and stability of nucleic acid bases and base pairs Hydration and stability of nucleic acid bases and base pairs
skos:prefLabel
Hydratace a stabilita bází nukleových kyselin a jejich párů Hydration and stability of nucleic acid bases and base pairs Hydration and stability of nucleic acid bases and base pairs
skos:notation
RIV/61388963:_____/07:00090323!RIV08-AV0-61388963
n3:strany
903;917
n3:aktivita
n5:Z n5:P
n3:aktivity
P(GA203/05/0009), P(KJB400550518), P(LC512), Z(AV0Z40550506)
n3:cisloPeriodika
8
n3:dodaniDat
n12:2008
n3:domaciTvurceVysledku
n16:1890646 n16:2932016
n3:druhVysledku
n11:J
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
425058
n3:idVysledku
RIV/61388963:_____/07:00090323
n3:jazykVysledku
n17:eng
n3:klicovaSlova
hydratation; nucleic acid base; base pairs; stacking; H-bonding
n3:klicoveSlovo
n4:H-bonding n4:hydratation n4:base%20pairs n4:stacking n4:nucleic%20acid%20base
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[E3B41647EE28]
n3:nazevZdroje
Physical Chemistry Chemical Physics
n3:obor
n14:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n10:KJB400550518 n10:GA203%2F05%2F0009 n10:LC512
n3:rokUplatneniVysledku
n12:2007
n3:svazekPeriodika
9
n3:tvurceVysledku
Kabeláč, Martin Hobza, Pavel
n3:zamer
n18:AV0Z40550506
s:issn
1463-9076
s:numberOfPages
15