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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F07%3A00089578%21RIV08-AV0-61388963
rdf:type
n13:Vysledek skos:Concept
dcterms:description
Complexes of the type [(CH3)Pt(L)]+ with L = pyridine (py), 2,2'-bipyridine (bipy), and 1,10-phenanthroline (phen) are capable of activating the C–H bond in methane as shown by H/D exchange when using CD4 as a neutral reactant. Most reactive is the complex [(CH3)Pt(py)]+ bearing a monodentate nitrogen ligand. Complexes of the type [(CH3)Pt(L)]+ with L = pyridine (py), 2,2'-bipyridine (bipy), and 1,10-phenanthroline (phen) are capable of activating the C–H bond in methane as shown by H/D exchange when using CD4 as a neutral reactant. Most reactive is the complex [(CH3)Pt(py)]+ bearing a monodentate nitrogen ligand. Komplexy typu [(CH3)Pt(L)]+, kde L = pyridin (py), 2,2'-bipyridin (bipy) a 1,10-fenantrolin (phen), jsou schopné aktivovat C–H vazbu v methanu jak ukazuje H/D výměna při reakci s CD4. Nejreaktivnější je komplex [(CH3)Pt(py)]+ nesoucí monodentátní dusíkový ligand.
dcterms:title
C–H Bond activation of methane with gaseous [(CH3)Pt(L)]+ complexes (L = pyridine, bipyridine, and phenanthroline) C–H Bond activation of methane with gaseous [(CH3)Pt(L)]+ complexes (L = pyridine, bipyridine, and phenanthroline) Aktivace C–H vazby methanu plynnými komplexy [(CH3)Pt(L)]+ (L = pyridin, bipyridin, a fenantrolin)
skos:prefLabel
Aktivace C–H vazby methanu plynnými komplexy [(CH3)Pt(L)]+ (L = pyridin, bipyridin, a fenantrolin) C–H Bond activation of methane with gaseous [(CH3)Pt(L)]+ complexes (L = pyridine, bipyridine, and phenanthroline) C–H Bond activation of methane with gaseous [(CH3)Pt(L)]+ complexes (L = pyridine, bipyridine, and phenanthroline)
skos:notation
RIV/61388963:_____/07:00089578!RIV08-AV0-61388963
n3:strany
309;311
n3:aktivita
n10:Z
n3:aktivity
Z(AV0Z40550506)
n3:cisloPeriodika
3
n3:dodaniDat
n15:2008
n3:domaciTvurceVysledku
Schröder, Detlef
n3:druhVysledku
n4:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
413174
n3:idVysledku
RIV/61388963:_____/07:00089578
n3:jazykVysledku
n14:eng
n3:klicovaSlova
C-H bond activation; electrospray ionization; mass spectrometry; methane; platinum
n3:klicoveSlovo
n7:electrospray%20ionization n7:mass%20spectrometry n7:methane n7:platinum n7:C-H%20bond%20activation
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[AB2FC2761FA2]
n3:nazevZdroje
Zeitschrift fur Naturforschung. Section B: a Journal of Chemical Sciences
n3:obor
n16:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n15:2007
n3:svazekPeriodika
62b
n3:tvurceVysledku
Schröder, Detlef Schlangen, M. Butschke, B. Schwarz, H.
n3:zamer
n11:AV0Z40550506
s:issn
0932-0776
s:numberOfPages
5