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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F07%3A00089489%21RIV08-AV0-61388963
rdf:type
skos:Concept n8:Vysledek
dcterms:description
Ionizace elektrosprejem methanolového roztoku Michlerovy modři, bis(4-(N,N-dimethylamino)fenyl)methyl tetrafluoroborate, 1+BF4–, poskytuje formální methanolový adukt [1+ .CH3OH], jež má neobvyklou chemii v plynné fázi. Výsledky také zpochybňují jinak úspěšnou kinetickou metodu. Electrospray ionization of a methanolic solution of Michler’s hydrol blue, bis(4-(N,N-dimethylamino)phenyl)methyl tetrafluoroborate, 1+BF4–, produces the formal methanol adduct [1+ .CH3OH], which shows an unusual gas-phase chemistry. The results also question the otherwise successful kinetic method. Electrospray ionization of a methanolic solution of Michler’s hydrol blue, bis(4-(N,N-dimethylamino)phenyl)methyl tetrafluoroborate, 1+BF4–, produces the formal methanol adduct [1+ .CH3OH], which shows an unusual gas-phase chemistry. The results also question the otherwise successful kinetic method.
dcterms:title
The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion Neočekávaná reaktivity CH3OH aduktu Michlerovy hydrolové modři v plynné fázi: katalýza přenosem protonu a postupná eliminace radikálů The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion
skos:prefLabel
The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion Neočekávaná reaktivity CH3OH aduktu Michlerovy hydrolové modři v plynné fázi: katalýza přenosem protonu a postupná eliminace radikálů The Unexpected gas-phase reactivity of the CH3OH adduct of Michler’s hydrol blue: Proton-shuttle catalysis and stepwise radical expulsion
skos:notation
RIV/61388963:_____/07:00089489!RIV08-AV0-61388963
n3:strany
8925;8933
n3:aktivita
n17:Z
n3:aktivity
Z(AV0Z40550506)
n3:cisloPeriodika
37
n3:dodaniDat
n14:2008
n3:domaciTvurceVysledku
n4:2213117 Schröder, Detlef
n3:druhVysledku
n10:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
456605
n3:idVysledku
RIV/61388963:_____/07:00089489
n3:jazykVysledku
n9:eng
n3:klicovaSlova
carbenium ions; electrospray ionization; mass spectrometry; proton transfer
n3:klicoveSlovo
n12:electrospray%20ionization n12:carbenium%20ions n12:proton%20transfer n12:mass%20spectrometry
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[0A09CBC3C76A]
n3:nazevZdroje
Journal of Physical Chemistry A
n3:obor
n7:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:rokUplatneniVysledku
n14:2007
n3:svazekPeriodika
111
n3:tvurceVysledku
Roithová, Jana Schwarz, H. Koszinowski, K. Mayr, H. Gruene, P. Schröder, Detlef
n3:zamer
n15:AV0Z40550506
s:issn
1089-5639
s:numberOfPages
9