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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F07%3A00088762%21RIV08-AV0-61388963
rdf:type
n17:Vysledek skos:Concept
dcterms:description
Byla popsána syntéza 2,6-bis[((3S)-3-(methoxycarbonyl)-1,2,3,4-tetrahydroisoquinolin- 2-yl)carbonyl]pyridinu a jeho koordinační sloučeniny s Cu2+, Co2+, Co3+, or Fe3+ ionty. Připravené komplexy byly testovány v enantioselektivní katalýze nitroaldolové adice nitormetanu s 2-nitrobenzaldehydem a 4-nitrobenzaldehyden a v adici ethyl-2-oxocyklohexanekarboxylatu. Syntheses of 2,6-bis[((3S)-3-(methoxycarbonyl)-1,2,3,4-tetrahydroisoquinolin- 2-yl)carbonyl]pyridine and its coordination compounds with Cu2+, Co2+, Co3+, or Fe3+ are described. The prepared coordination compounds were tested in the enantioselective catalysis of the nitroaldol addition of nitromethane with 2-nitrobenzaldehyde or 4-nitrobenzaldehyde, and in the Michael addition of ethyl 2-oxocyclohexanecarboxylate to but-3-en-2-one. Syntheses of 2,6-bis[((3S)-3-(methoxycarbonyl)-1,2,3,4-tetrahydroisoquinolin- 2-yl)carbonyl]pyridine and its coordination compounds with Cu2+, Co2+, Co3+, or Fe3+ are described. The prepared coordination compounds were tested in the enantioselective catalysis of the nitroaldol addition of nitromethane with 2-nitrobenzaldehyde or 4-nitrobenzaldehyde, and in the Michael addition of ethyl 2-oxocyclohexanecarboxylate to but-3-en-2-one.
dcterms:title
Coordination compounds based on 1,2,3,4-tetrahydro-isoquinoline-3-carboxylic acid Coordination compounds based on 1,2,3,4-tetrahydro-isoquinoline-3-carboxylic acid Koordinační sloučeniny 1,2,3,4-Tetrahydroisoquinoline-3-karboxylové kyseliny
skos:prefLabel
Coordination compounds based on 1,2,3,4-tetrahydro-isoquinoline-3-carboxylic acid Coordination compounds based on 1,2,3,4-tetrahydro-isoquinoline-3-carboxylic acid Koordinační sloučeniny 1,2,3,4-Tetrahydroisoquinoline-3-karboxylové kyseliny
skos:notation
RIV/61388963:_____/07:00088762!RIV08-AV0-61388963
n3:strany
1064;1079
n3:aktivita
n8:V n8:Z n8:P
n3:aktivity
P(LC512), V, Z(AV0Z40550506), Z(MSM0021627501)
n3:cisloPeriodika
5
n3:dodaniDat
n7:2008
n3:domaciTvurceVysledku
n14:1747681 n14:5941814
n3:druhVysledku
n12:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
415083
n3:idVysledku
RIV/61388963:_____/07:00088762
n3:jazykVysledku
n18:eng
n3:klicovaSlova
coordination compounds; DFT; chiral Tic acid derivatives; enantioselective catalysis
n3:klicoveSlovo
n5:coordination%20compounds n5:enantioselective%20catalysis n5:chiral%20Tic%20acid%20derivatives n5:DFT
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[B452DA72ED0E]
n3:nazevZdroje
Molecules
n3:obor
n16:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:projekt
n13:LC512
n3:rokUplatneniVysledku
n7:2007
n3:svazekPeriodika
12
n3:tvurceVysledku
Svobodová, M. Nachtigall, Petr Macháček, V. Wsól, V. Jansa, Petr
n3:zamer
n11:MSM0021627501 n11:AV0Z40550506
s:issn
1420-3049
s:numberOfPages
16