This HTML5 document contains 50 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n12http://linked.opendata.cz/resource/domain/vavai/projekt/
n4http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n7http://linked.opendata.cz/ontology/domain/vavai/
n10http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n17http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61388963%3A_____%2F06%3A00040683%21RIV07-AV0-61388963/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n8http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n6http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n18http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n11http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n15http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F06%3A00040683%21RIV07-AV0-61388963
rdf:type
skos:Concept n7:Vysledek
dcterms:description
The keto–enol tautomerization of 7-methyl-guanine and 9-methyl-guanine in the excited states (due to p - p* and n - p* transitions) was investigated using the time-dependent DFT (TDDFT) method. The state of the n - p* transition exhibits two minima whith the second being intermediate between enol and keto tautomers. This structure, is observed in both species, which suggests that it cannot account alone for their different photophysical behavior. The keto–enol tautomerization of 7-methyl-guanine and 9-methyl-guanine in the excited states (due to p - p* and n - p* transitions) was investigated using the time-dependent DFT (TDDFT) method. The state of the n - p* transition exhibits two minima whith the second being intermediate between enol and keto tautomers. This structure, is observed in both species, which suggests that it cannot account alone for their different photophysical behavior. Keto enol tautomerizace 7-methyl-guaninu and 9-methyl-guaninu v excitovaných stavech (p - p* a n - p*) byla studována časově závislou DFT metodou (TDDFT). Byla nalezena dvě minima pro stav n - p*, přičemž druhé minimum je pravděpodobně meziproduktem mezi keto a enol formou. Tato struktura byla pozorována pro oba konforméry, takže nemůže vysvětlovat jejich rozdílné fotofyzikální chování.
dcterms:title
Theoretical study of the ground and excited states of 7-methyl guanine and 9-methyl guanine: comparison with experiment Teoretická studie základního excitovaného stavu 7-methyl guaninu and 9-methyl guaninu: srovnání s experimentem Theoretical study of the ground and excited states of 7-methyl guanine and 9-methyl guanine: comparison with experiment
skos:prefLabel
Teoretická studie základního excitovaného stavu 7-methyl guaninu and 9-methyl guaninu: srovnání s experimentem Theoretical study of the ground and excited states of 7-methyl guanine and 9-methyl guanine: comparison with experiment Theoretical study of the ground and excited states of 7-methyl guanine and 9-methyl guanine: comparison with experiment
skos:notation
RIV/61388963:_____/06:00040683!RIV07-AV0-61388963
n3:strany
3059;3065
n3:aktivita
n18:P n18:Z
n3:aktivity
P(GA203/05/0009), P(LC512), Z(AV0Z4055905)
n3:cisloPeriodika
26
n3:dodaniDat
n15:2007
n3:domaciTvurceVysledku
n4:9831339 n4:5461162 n4:2932016 n4:5865875
n3:druhVysledku
n16:J
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
503703
n3:idVysledku
RIV/61388963:_____/06:00040683
n3:jazykVysledku
n11:eng
n3:klicovaSlova
TDDFT; excitated states; guanine tautomers
n3:klicoveSlovo
n8:excitated%20states n8:guanine%20tautomers n8:TDDFT
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[C95F89E0C6FA]
n3:nazevZdroje
Physical Chemistry Chemical Physics
n3:obor
n9:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
5
n3:projekt
n12:LC512 n12:GA203%2F05%2F0009
n3:rokUplatneniVysledku
n15:2006
n3:svazekPeriodika
8
n3:tvurceVysledku
Špirko, Vladimír Nachtigallová, Dana Mons, M. Hobza, Pavel Černý, Jiří
n3:zamer
n10:AV0Z4055905
s:issn
1463-9076
s:numberOfPages
7