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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F05%3A00021100%21RIV06-MSM-61388963
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Linear oligoesters based on etienic acid(3beta-hydroxyandrost-5-ene-17beta-carboxylic acid) containing four steroid units were prepared using a 2+2 synthetic strategy in a successful synthesis of 3beta-{[3beta-({3beta-[(3beta-hydroxyandrost-5-ene-17beta-carbonyl)oxy]androst-5-ene-17beta-carbonyl}oxy)androst-5-ene-17beta-carbonyl]oxy}androst-5-ene-17beta-carboxylic acid. the main problems with deprotection were overcome by using orthogonal groups as O-nitrates and 2-(trimethylsilyl)ethyl ethers. Lineární oligomery obsahující 4 jednotky kyseliny etienové (3beta-hydroxyandrost-5-en-17beta-karboxylové kyseliny) byly připraveny využitím 2+2 strategie vedoucí k 3beta-{[3beta-({3beta-[(3beta-hydroxyandrost-5-en-17beta-karbonyl)oxy]androst-5-en-17beta-karbonyl}oxy)androst-5-en-17beta-karbonyl]oxy}androst-5-en-17beta-karboxylové kyseliny. Problémy se štěpením chránicích skupin byly překonány použitím ortogonálních skupin O-nitrátu a 2-(trimethylsilyl)ethyl esteru. Linear oligoesters based on etienic acid(3beta-hydroxyandrost-5-ene-17beta-carboxylic acid) containing four steroid units were prepared using a 2+2 synthetic strategy in a successful synthesis of 3beta-{[3beta-({3beta-[(3beta-hydroxyandrost-5-ene-17beta-carbonyl)oxy]androst-5-ene-17beta-carbonyl}oxy)androst-5-ene-17beta-carbonyl]oxy}androst-5-ene-17beta-carboxylic acid. the main problems with deprotection were overcome by using orthogonal groups as O-nitrates and 2-(trimethylsilyl)ethyl ethers.
dcterms:title
Etienic etienate as synthon for the synthesis of steroid oligoester gelators Etienyl etienát jako synthon pro přípravu steroidních oligomerních gelátorů Etienic etienate as synthon for the synthesis of steroid oligoester gelators
skos:prefLabel
Etienyl etienát jako synthon pro přípravu steroidních oligomerních gelátorů Etienic etienate as synthon for the synthesis of steroid oligoester gelators Etienic etienate as synthon for the synthesis of steroid oligoester gelators
skos:notation
RIV/61388963:_____/05:00021100!RIV06-MSM-61388963
n3:strany
615;625
n3:aktivita
n10:Z n10:P
n3:aktivity
P(1P04OCD31.001), Z(AV0Z40550506), Z(MSM6046137305)
n3:cisloPeriodika
-
n3:dodaniDat
n8:2006
n3:domaciTvurceVysledku
n5:8009406 n5:6665411 n5:9923047 n5:3427668 n5:6236219
n3:druhVysledku
n14:J
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
520597
n3:idVysledku
RIV/61388963:_____/05:00021100
n3:jazykVysledku
n13:eng
n3:klicovaSlova
oligomers; etienyl etienate; gelators
n3:klicoveSlovo
n12:etienyl%20etienate n12:oligomers n12:gelators
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[A84472782FB8]
n3:nazevZdroje
Steroids
n3:obor
n17:CC
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:projekt
n16:1P04OCD31.001
n3:rokUplatneniVysledku
n8:2005
n3:svazekPeriodika
70
n3:tvurceVysledku
Drašar, Pavel Černý, Ivan Pouzar, Vladimír Buděšínský, Miloš Reschel, Miroslav
n3:zamer
n7:AV0Z40550506 n7:MSM6046137305
s:issn
0039-128X
s:numberOfPages
11