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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F05%3A00020908%21RIV06-GA0-61388963
rdf:type
skos:Concept n16:Vysledek
dcterms:description
To investigate the role of UV irradiation in base-pairing we have studied guanine (G) and cytosine(C) base pairs. We distinguished base-pair structures by IR-UV hole-burning spectroscopy as well as by high-level correlated ab initio calculations. The Watson-Crick structure exhibits broad UV absorption, in stark contrast to other GC structures and other base-pair structures. This broad absorption may be explained by a rapid internal conversion that makes this specific base pair arrangement uniquely photochemically stable. Spektroskopické vlastnosti páru bazí guanin-cytosin byly studovány pomocí experimentálních (IČ a UV spektroskopie) a teoretických (přesné korelované kvantově-chemické výpočty) metod. Watson-Crickovská struktura tohoto páru bází vykazuje narozdíl od ostatních struktur tohoto páru širokou specifickou UV absorbci, která může být vysvětlena velmi rychlou vnitřní konverzí. To investigate the role of UV irradiation in base-pairing we have studied guanine (G) and cytosine(C) base pairs. We distinguished base-pair structures by IR-UV hole-burning spectroscopy as well as by high-level correlated ab initio calculations. The Watson-Crick structure exhibits broad UV absorption, in stark contrast to other GC structures and other base-pair structures. This broad absorption may be explained by a rapid internal conversion that makes this specific base pair arrangement uniquely photochemically stable.
dcterms:title
Photochemická selektivita v páru bazí guanin-cytosine Photochemical selectivity in guanine-cytosine base-pair structures Photochemical selectivity in guanine-cytosine base-pair structures
skos:prefLabel
Photochemical selectivity in guanine-cytosine base-pair structures Photochemical selectivity in guanine-cytosine base-pair structures Photochemická selektivita v páru bazí guanin-cytosine
skos:notation
RIV/61388963:_____/05:00020908!RIV06-GA0-61388963
n4:strany
20;23
n4:aktivita
n12:Z n12:P
n4:aktivity
P(GA203/05/0009), Z(AV0Z40550506)
n4:cisloPeriodika
1
n4:dodaniDat
n6:2006
n4:domaciTvurceVysledku
n14:1890646 n14:2932016
n4:druhVysledku
n15:J
n4:duvernostUdaju
n13:S
n4:entitaPredkladatele
n17:predkladatel
n4:idSjednocenehoVysledku
535920
n4:idVysledku
RIV/61388963:_____/05:00020908
n4:jazykVysledku
n18:eng
n4:klicovaSlova
DNA base pairs; IR-UV spectroscopy; phytochemistry
n4:klicoveSlovo
n7:phytochemistry n7:IR-UV%20spectroscopy n7:DNA%20base%20pairs
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[9810DAE801A5]
n4:nazevZdroje
Proceedings of the National Academy of Sciences of the United States of America
n4:obor
n10:CF
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
6
n4:projekt
n9:GA203%2F05%2F0009
n4:rokUplatneniVysledku
n6:2005
n4:svazekPeriodika
102
n4:tvurceVysledku
Grace, L. Hobza, Pavel Kabeláč, Martin Vries de, M. S. Abo-Riziq, A. Nir, E.
n4:zamer
n11:AV0Z40550506
s:issn
0027-8424
s:numberOfPages
4