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Statements

Subject Item
n2:RIV%2F61388963%3A_____%2F05%3A00020898%21RIV06-GA0-61388963
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Stabilization energies of the H-bonded and stacked structures of a DNA base pair were studied in the crystal structures of adenine-thymine, cytosine-guanine, and adenine-cytosine steps as well as in the 5'-d(GCGAAGC)-3'hairpin (utilizing the NMR geometry). The stacking accounts for a significant part of the overall stabilization. It contributes equally to the stability of DNA as does H-bonding for AT rich DNAs while in the case of GC rich DNAs it forms about one third of the total stabilization. Stabilization energies of the H-bonded and stacked structures of a DNA base pair were studied in the crystal structures of adenine-thymine, cytosine-guanine, and adenine-cytosine steps as well as in the 5'-d(GCGAAGC)-3'hairpin (utilizing the NMR geometry). The stacking accounts for a significant part of the overall stabilization. It contributes equally to the stability of DNA as does H-bonding for AT rich DNAs while in the case of GC rich DNAs it forms about one third of the total stabilization. Byly studovány stabilizační energie vodíkově vázaných a disperzně vázaných párů bazí v geometriích vzatých z krystalových struktur i z NMR studií (5'-d(GCGAAGC)-3'hairpin). V sekvencích bohatých na adenin a thymin přispívá disperzní (stack) interakce k celkové stabilitě stejnou měrou jako vazba vodíkovými vazbami. V GC bohatých sekvencích tvoří disperzní interakce přibližně třetinu celkové interakční energie.
dcterms:title
Stabilization energies of the hydrogen-bonded and stacked structures of nucleic acid base pairs in the crystal geometries of CG, AT, and AC DNA steps and in the NMR geometry of the 5'-d(GCGAAGC)-3' hairpin: Complete basis set calculations at the MP2 a... Stabilization energies of the hydrogen-bonded and stacked structures of nucleic acid base pairs in the crystal geometries of CG, AT, and AC DNA steps and in the NMR geometry of the 5'-d(GCGAAGC)-3' hairpin: Complete basis set calculations at the MP2 a... Stabilizační energie vodíkově a disperzně vázaných párů bazí nukleových kyselin v krystalových geometriích a v NMR geometrii hairpinu 5'-d(GCGAAGC)-3': Výpočty v úplné bázové limitě metodami MP2 a CCSD(T)
skos:prefLabel
Stabilization energies of the hydrogen-bonded and stacked structures of nucleic acid base pairs in the crystal geometries of CG, AT, and AC DNA steps and in the NMR geometry of the 5'-d(GCGAAGC)-3' hairpin: Complete basis set calculations at the MP2 a... Stabilizační energie vodíkově a disperzně vázaných párů bazí nukleových kyselin v krystalových geometriích a v NMR geometrii hairpinu 5'-d(GCGAAGC)-3': Výpočty v úplné bázové limitě metodami MP2 a CCSD(T) Stabilization energies of the hydrogen-bonded and stacked structures of nucleic acid base pairs in the crystal geometries of CG, AT, and AC DNA steps and in the NMR geometry of the 5'-d(GCGAAGC)-3' hairpin: Complete basis set calculations at the MP2 a...
skos:notation
RIV/61388963:_____/05:00020898!RIV06-GA0-61388963
n5:strany
1131;1136
n5:aktivita
n14:P n14:Z
n5:aktivity
P(GA203/05/0009), Z(AV0Z40550506)
n5:cisloPeriodika
-
n5:dodaniDat
n15:2006
n5:domaciTvurceVysledku
n7:3843912 n7:2932016
n5:druhVysledku
n13:J
n5:duvernostUdaju
n16:S
n5:entitaPredkladatele
n18:predkladatel
n5:idSjednocenehoVysledku
544223
n5:idVysledku
RIV/61388963:_____/05:00020898
n5:jazykVysledku
n6:eng
n5:klicovaSlova
base pairs; complete basis set; DNA
n5:klicoveSlovo
n9:complete%20basis%20set n9:DNA n9:base%20pairs
n5:kodStatuVydavatele
US - Spojené státy americké
n5:kontrolniKodProRIV
[3088A642DE3F]
n5:nazevZdroje
Journal of Physical Chemistry. A
n5:obor
n10:CF
n5:pocetDomacichTvurcuVysledku
2
n5:pocetTvurcuVysledku
4
n5:projekt
n11:GA203%2F05%2F0009
n5:rokUplatneniVysledku
n15:2005
n5:svazekPeriodika
109
n5:tvurceVysledku
Dabkowska, I. Jurečka, Petr Gonzalez, H. V. Hobza, Pavel
n5:zamer
n12:AV0Z40550506
s:issn
1089-5639
s:numberOfPages
6