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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F14%3A00434756%21RIV15-AV0-61388955
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is %22hemiracemic%22 and 2 and 4 are %22fully racemic%22 compounds. Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is %22hemiracemic%22 and 2 and 4 are %22fully racemic%22 compounds.
dcterms:title
Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations
skos:prefLabel
Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations
skos:notation
RIV/61388955:_____/14:00434756!RIV15-AV0-61388955
n4:aktivita
n10:I
n4:aktivity
I
n4:cisloPeriodika
8
n4:dodaniDat
n14:2015
n4:domaciTvurceVysledku
n16:5347440
n4:druhVysledku
n11:J
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n8:predkladatel
n4:idSjednocenehoVysledku
22269
n4:idVysledku
RIV/61388955:_____/14:00434756
n4:jazykVysledku
n5:eng
n4:klicovaSlova
RACEMIC COMPOUND FORMATION; TRIS(DIIMINE)-METAL COMPLEXES; CONGLOMERATE FORMATION
n4:klicoveSlovo
n6:CONGLOMERATE%20FORMATION n6:TRIS%28DIIMINE%29-METAL%20COMPLEXES n6:RACEMIC%20COMPOUND%20FORMATION
n4:kodStatuVydavatele
NL - Nizozemsko
n4:kontrolniKodProRIV
[955923C068D1]
n4:nazevZdroje
Transition Metal Chemistry
n4:obor
n13:CF
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
5
n4:rokUplatneniVysledku
n14:2014
n4:svazekPeriodika
39
n4:tvurceVysledku
Antal, P. Tatiersky, J. Drábik, M. Schwendt, P. Gyepes, Robert
n4:wos
000343836900007
s:issn
0340-4285
s:numberOfPages
8
n15:doi
10.1007/s11243-014-9873-2