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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F14%3A00395692%21RIV15-GA0-61388955
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Analysis of cyclic voltammograms of Li insertion into TiO2 (B) and anatase provides information about capacitive contributions to overall charge of Li-storage. The enhancement of 30% is found in capacitive contributions (normalized to the total stored charges) in TiO2 (B) compared to that in anatase, in spite of ca. three times smaller surface area of the former. Different charging mechanism explains facilitated Liþ insertion in TiO2 (B). The difference is caused mainly by pseudocapacitive Li-storage in the bulk TiO2 (B). Deconvolution of cyclic voltammograms also indicates different capacitive contributions of the two voltammetric peaks, S1 and S2 of TiO2 (B). These results provide novel insight into the Li-storage in TiO2 (B) and its difference from that in anatase. Analysis of cyclic voltammograms of Li insertion into TiO2 (B) and anatase provides information about capacitive contributions to overall charge of Li-storage. The enhancement of 30% is found in capacitive contributions (normalized to the total stored charges) in TiO2 (B) compared to that in anatase, in spite of ca. three times smaller surface area of the former. Different charging mechanism explains facilitated Liþ insertion in TiO2 (B). The difference is caused mainly by pseudocapacitive Li-storage in the bulk TiO2 (B). Deconvolution of cyclic voltammograms also indicates different capacitive contributions of the two voltammetric peaks, S1 and S2 of TiO2 (B). These results provide novel insight into the Li-storage in TiO2 (B) and its difference from that in anatase.
dcterms:title
Capacitive contribution to Li-storage in TiO2 (B) and TiO2 (anatase) Capacitive contribution to Li-storage in TiO2 (B) and TiO2 (anatase)
skos:prefLabel
Capacitive contribution to Li-storage in TiO2 (B) and TiO2 (anatase) Capacitive contribution to Li-storage in TiO2 (B) and TiO2 (anatase)
skos:notation
RIV/61388955:_____/14:00395692!RIV15-GA0-61388955
n3:aktivita
n15:P n15:I
n3:aktivity
I, P(GA13-07724S), P(GAP108/12/0814)
n3:cisloPeriodika
JAN 2014
n3:dodaniDat
n9:2015
n3:domaciTvurceVysledku
n8:5808111 n8:9704418 n8:5401070 n8:5283396 n8:5876400
n3:druhVysledku
n11:J
n3:duvernostUdaju
n5:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
6163
n3:idVysledku
RIV/61388955:_____/14:00395692
n3:jazykVysledku
n16:eng
n3:klicovaSlova
titanium dioxide; TiO2 (B); Li-insertion
n3:klicoveSlovo
n13:TiO2%20%28B%29 n13:Li-insertion n13:titanium%20dioxide
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[16A10B50873C]
n3:nazevZdroje
Journal of Power Sources
n3:obor
n6:CG
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:projekt
n4:GAP108%2F12%2F0814 n4:GA13-07724S
n3:rokUplatneniVysledku
n9:2014
n3:svazekPeriodika
246
n3:tvurceVysledku
Lásková, Barbora Zukal, Arnošt Zukalová, Markéta Bouša, Milan Kavan, Ladislav
n3:wos
000326661100015
s:issn
0378-7753
s:numberOfPages
7
n14:doi
10.1016/j.jpowsour.2013.07.073