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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F13%3A00422330%21RIV14-GA0-61388955
rdf:type
skos:Concept n13:Vysledek
dcterms:description
This contribution reports new methodology we have developed for the disassembly of 3-D UTL framework into 2-D lamellae followed by structure modification including pillaring. This may be widely applicable, particularly to other zeolites that have D4R units present, and so should have great impact also on other porous solids. Specifically, controlled hydrolysis of D4R units in the interlayer space provides individual ultrathin layers with UTL structure by a chemically selective method. Further manipulation of the layers gives a completely novel approach (3D to 2D to pillared) offering hitherto unprecedented opportunities for the preparation of modified zeolites with diverse chemical and structural properties. This contribution reports new methodology we have developed for the disassembly of 3-D UTL framework into 2-D lamellae followed by structure modification including pillaring. This may be widely applicable, particularly to other zeolites that have D4R units present, and so should have great impact also on other porous solids. Specifically, controlled hydrolysis of D4R units in the interlayer space provides individual ultrathin layers with UTL structure by a chemically selective method. Further manipulation of the layers gives a completely novel approach (3D to 2D to pillared) offering hitherto unprecedented opportunities for the preparation of modified zeolites with diverse chemical and structural properties.
dcterms:title
3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials
skos:prefLabel
3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials 3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials
skos:notation
RIV/61388955:_____/13:00422330!RIV14-GA0-61388955
n13:predkladatel
n14:ico%3A61388955
n3:aktivita
n18:P n18:I
n3:aktivity
I, P(GA203/08/0604), P(GAP106/12/0189)
n3:cisloPeriodika
4
n3:dodaniDat
n6:2014
n3:domaciTvurceVysledku
n9:7713452 n9:7016662 Roth, Wieslaw Jerzy n9:5283396
n3:druhVysledku
n16:J
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
119809
n3:idVysledku
RIV/61388955:_____/13:00422330
n3:jazykVysledku
n15:eng
n3:klicovaSlova
ultrathin zeolites; UTL zeolite; IPC-1PI
n3:klicoveSlovo
n4:UTL%20zeolite n4:ultrathin%20zeolites n4:IPC-1PI
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[0E6EE8EFB8FA]
n3:nazevZdroje
Chemistry of Materials
n3:obor
n5:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
8
n3:projekt
n8:GAP106%2F12%2F0189 n8:GA203%2F08%2F0604
n3:rokUplatneniVysledku
n6:2013
n3:svazekPeriodika
25
n3:tvurceVysledku
Čejka, Jiří Shvets, O. V. Roth, Wieslaw Jerzy Zukal, Arnošt Zhou, W. Morris, R. E. Greer, H. F. Chlubná, Pavla
n3:wos
000315618500005
s:issn
0897-4756
s:numberOfPages
6
n17:doi
10.1021/cm303260z