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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F13%3A00395897%21RIV14-GA0-61388955
rdf:type
n5:Vysledek skos:Concept
dcterms:description
This review focuses on the use of metal organic frameworks (MOFs) as catalysts for the synthesis of fine chemicals. While petrochemistry is characterized by gas phase reactions, in which MOFs cannot compete with robust zeolites, MOFs are better suited for liquid phase reactions performed at moderate temperatures. These are the conditions typically employed for the production of fine chemicals characterized by being more complex and diverse molecules of low volatility, but with high added value. For the preparation of this type of compound, MOFs offer the advantage of wide open porosity in the nanometer scale and a large void volume. In the present review we have summarized the reports that appeared up to early 2013 on the use of MOFs as catalysts in the liquid phase for the production of fine chemicals, primarily classified according to the type of active site and the functional group formed in the reaction. Prospects for future development in this field are provided in the last section. This review focuses on the use of metal organic frameworks (MOFs) as catalysts for the synthesis of fine chemicals. While petrochemistry is characterized by gas phase reactions, in which MOFs cannot compete with robust zeolites, MOFs are better suited for liquid phase reactions performed at moderate temperatures. These are the conditions typically employed for the production of fine chemicals characterized by being more complex and diverse molecules of low volatility, but with high added value. For the preparation of this type of compound, MOFs offer the advantage of wide open porosity in the nanometer scale and a large void volume. In the present review we have summarized the reports that appeared up to early 2013 on the use of MOFs as catalysts in the liquid phase for the production of fine chemicals, primarily classified according to the type of active site and the functional group formed in the reaction. Prospects for future development in this field are provided in the last section.
dcterms:title
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
skos:prefLabel
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
skos:notation
RIV/61388955:_____/13:00395897!RIV14-GA0-61388955
n5:predkladatel
n11:ico%3A61388955
n3:aktivita
n6:P n6:I
n3:aktivity
I, P(GBP106/12/G015)
n3:cisloPeriodika
10
n3:dodaniDat
n12:2014
n3:domaciTvurceVysledku
Opanasenko, Maksym n15:7016662
n3:druhVysledku
n18:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
87490
n3:idVysledku
RIV/61388955:_____/13:00395897
n3:jazykVysledku
n9:eng
n3:klicovaSlova
FRIEDEL-CRAFTS ACYLATION; CALCIUM-CHANNEL BLOCKERS; LIQUID-PHASE OXIDATIONS
n3:klicoveSlovo
n4:CALCIUM-CHANNEL%20BLOCKERS n4:LIQUID-PHASE%20OXIDATIONS n4:FRIEDEL-CRAFTS%20ACYLATION
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[57E983BA6C62]
n3:nazevZdroje
Catalysis Science &Technology
n3:obor
n10:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
4
n3:projekt
n8:GBP106%2F12%2FG015
n3:rokUplatneniVysledku
n12:2013
n3:svazekPeriodika
3
n3:tvurceVysledku
Čejka, Jiří Dhakshinamoorthy, A. Opanasenko, Maksym Garcia, H.
n3:wos
000324404000004
s:issn
2044-4753
s:numberOfPages
32
n19:doi
10.1039/C3CY00350G