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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F13%3A00391989%21RIV14-AV0-61388955
rdf:type
skos:Concept n12:Vysledek
dcterms:description
Two new compounds containing chiral cations and anions, [M(bpy)(3)][VO(O-2)(ox)(bpy)](2)center dot 7H(2)O (M = Fe, Ni; bpy = 2,2'-bipyridine; ox = oxalato(2-)) have been prepared and characterized by elemental analysis, vibrational spectra in the solid state, and by V-51 NMR and electronic spectroscopy in solution. The compounds are isostructural and racemic. The crystal structure contains two kinds of alternating (homochiral) triple layers: (i) the layer formed by Delta-[M(bpy)(3)](2+) cations intercalated between two layers of A-[VO(O-2)(ox)(bpy)](-), and (ii) the layer formed by Lambda-[M(bpy)(3)](2+) cations intercalated between two layers of B-[VO(O-2)(ox)(bpy)](-) (A- and B-denote different enantiomers of anions). Two new compounds containing chiral cations and anions, [M(bpy)(3)][VO(O-2)(ox)(bpy)](2)center dot 7H(2)O (M = Fe, Ni; bpy = 2,2'-bipyridine; ox = oxalato(2-)) have been prepared and characterized by elemental analysis, vibrational spectra in the solid state, and by V-51 NMR and electronic spectroscopy in solution. The compounds are isostructural and racemic. The crystal structure contains two kinds of alternating (homochiral) triple layers: (i) the layer formed by Delta-[M(bpy)(3)](2+) cations intercalated between two layers of A-[VO(O-2)(ox)(bpy)](-), and (ii) the layer formed by Lambda-[M(bpy)(3)](2+) cations intercalated between two layers of B-[VO(O-2)(ox)(bpy)](-) (A- and B-denote different enantiomers of anions).
dcterms:title
Supramolecular interactions between chiral ions: Synthesis and characterization of [M-II(bpy)(3)][VO(O-2)(ox)(bpy)].7H(2)O (M = Fe and Ni) Supramolecular interactions between chiral ions: Synthesis and characterization of [M-II(bpy)(3)][VO(O-2)(ox)(bpy)].7H(2)O (M = Fe and Ni)
skos:prefLabel
Supramolecular interactions between chiral ions: Synthesis and characterization of [M-II(bpy)(3)][VO(O-2)(ox)(bpy)].7H(2)O (M = Fe and Ni) Supramolecular interactions between chiral ions: Synthesis and characterization of [M-II(bpy)(3)][VO(O-2)(ox)(bpy)].7H(2)O (M = Fe and Ni)
skos:notation
RIV/61388955:_____/13:00391989!RIV14-AV0-61388955
n12:predkladatel
n18:ico%3A61388955
n5:aktivita
n14:I
n5:aktivity
I
n5:cisloPeriodika
JAN 2013
n5:dodaniDat
n9:2014
n5:domaciTvurceVysledku
n7:5347440
n5:druhVysledku
n8:J
n5:duvernostUdaju
n16:S
n5:entitaPredkladatele
n11:predkladatel
n5:idSjednocenehoVysledku
109060
n5:idVysledku
RIV/61388955:_____/13:00391989
n5:jazykVysledku
n6:eng
n5:klicovaSlova
vanadium(V); iron(II); nickel(II) complexes
n5:klicoveSlovo
n15:nickel%28II%29%20complexes n15:iron%28II%29 n15:vanadium%28V%29
n5:kodStatuVydavatele
NL - Nizozemsko
n5:kontrolniKodProRIV
[E0A36D8DEAB0]
n5:nazevZdroje
Journal of Molecular Structure
n5:obor
n17:CF
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
5
n5:rokUplatneniVysledku
n9:2013
n5:svazekPeriodika
1032
n5:tvurceVysledku
Gyepes, Robert Schwendt, P. Antal, P. Žák, Z. Tatiersky, J.
n5:wos
000313601100036
s:issn
0022-2860
s:numberOfPages
6
n13:doi
10.1016/j.molstruc.2012.10.019