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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F13%3A00389149%21RIV14-GA0-61388955
rdf:type
n14:Vysledek skos:Concept
dcterms:description
Catalytic activity of CuBTC and FeBTC was investigated in Beckmann rearrangement of a series of aromatic and non-aromatic oximes and compared with that of zeolites Beta and USY. The reactivity of substrates in Beckmann rearrangement increases in the order camphor oxime < cyclohexanone oxime < indanone oxime < acetophenone oxime. While zeolites show higher activity in the transformation of relatively small aromatic (acetophenone oxime, indanone oxime) and non-aromatic oximes (cyclohexanone oxime) providing 100% selectivity to the target lactams in all reactions, CuBTC was the most active in transformation of bulky oximes. It was deduced, that textural preferences of CuBTC may be the reason of its capability to facilitate the transformation of bulky camphor oxime in comparison with zeolites Beta and USY. Catalytic activity of CuBTC and FeBTC was investigated in Beckmann rearrangement of a series of aromatic and non-aromatic oximes and compared with that of zeolites Beta and USY. The reactivity of substrates in Beckmann rearrangement increases in the order camphor oxime < cyclohexanone oxime < indanone oxime < acetophenone oxime. While zeolites show higher activity in the transformation of relatively small aromatic (acetophenone oxime, indanone oxime) and non-aromatic oximes (cyclohexanone oxime) providing 100% selectivity to the target lactams in all reactions, CuBTC was the most active in transformation of bulky oximes. It was deduced, that textural preferences of CuBTC may be the reason of its capability to facilitate the transformation of bulky camphor oxime in comparison with zeolites Beta and USY.
dcterms:title
The effect of substrate size in the Beckmann rearrangement: MOFs vs. zeolites The effect of substrate size in the Beckmann rearrangement: MOFs vs. zeolites
skos:prefLabel
The effect of substrate size in the Beckmann rearrangement: MOFs vs. zeolites The effect of substrate size in the Beckmann rearrangement: MOFs vs. zeolites
skos:notation
RIV/61388955:_____/13:00389149!RIV14-GA0-61388955
n14:predkladatel
n18:ico%3A61388955
n3:aktivita
n4:I n4:P
n3:aktivity
I, P(GBP106/12/G015)
n3:cisloPeriodika
APR 2013
n3:dodaniDat
n13:2014
n3:domaciTvurceVysledku
Opanasenko, Maksym n5:7016662 n5:6769330
n3:druhVysledku
n8:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
71758
n3:idVysledku
RIV/61388955:_____/13:00389149
n3:jazykVysledku
n17:eng
n3:klicovaSlova
Beckmann rearrangement; oximes; CuBTC
n3:klicoveSlovo
n16:Beckmann%20rearrangement n16:oximes n16:CuBTC
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[B09E46CC9311]
n3:nazevZdroje
Catalysis Today
n3:obor
n10:CF
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
4
n3:projekt
n6:GBP106%2F12%2FG015
n3:rokUplatneniVysledku
n13:2013
n3:svazekPeriodika
204
n3:tvurceVysledku
Lamač, Martin Shamzy, M. V. Čejka, Jiří Opanasenko, Maksym
n3:wos
000314825900014
s:issn
0920-5861
s:numberOfPages
7
n19:doi
10.1016/j.cattod.2012.09.008