This HTML5 document contains 46 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n18http://linked.opendata.cz/resource/domain/vavai/projekt/
n10http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n9http://linked.opendata.cz/resource/domain/vavai/subjekt/
n8http://linked.opendata.cz/ontology/domain/vavai/
n7http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n14http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n17http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61388955%3A_____%2F12%3A00375913%21RIV13-GA0-61388955/
n4http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n5http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n20http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n19http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F12%3A00375913%21RIV13-GA0-61388955
rdf:type
skos:Concept n8:Vysledek
dcterms:description
Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion of benzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction. Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion of benzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction.
dcterms:title
High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride
skos:prefLabel
High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride
skos:notation
RIV/61388955:_____/12:00375913!RIV13-GA0-61388955
n8:predkladatel
n9:ico%3A61388955
n3:aktivita
n20:P n20:Z
n3:aktivity
P(GA104/07/0383), Z(AV0Z40400503)
n3:cisloPeriodika
1
n3:dodaniDat
n19:2013
n3:domaciTvurceVysledku
n10:7106351 n10:7016662
n3:druhVysledku
n15:J
n3:duvernostUdaju
n5:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
138915
n3:idVysledku
RIV/61388955:_____/12:00375913
n3:jazykVysledku
n16:eng
n3:klicovaSlova
acylation; p-xylene; zeolites
n3:klicoveSlovo
n4:p-xylene n4:zeolites n4:acylation
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[5857E1B3F795]
n3:nazevZdroje
Catalysis Today
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:projekt
n18:GA104%2F07%2F0383
n3:rokUplatneniVysledku
n19:2012
n3:svazekPeriodika
179
n3:tvurceVysledku
Čejka, Jiří Kurfiřtová, Lenka Chang, J. - S. Hwang, Y. K. Seo, Y. - K.
n3:wos
000298404600011
n3:zamer
n7:AV0Z40400503
s:issn
0920-5861
s:numberOfPages
6
n14:doi
10.1016/j.cattod.2011.08.001