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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F11%3A00377571%21RIV13-GA0-61388955
rdf:type
skos:Concept n13:Vysledek
dcterms:description
In d.c. voltammetry of dilute aqueous chloroauric acid with hanging mercury drop electrode, when potential scanning proceeds from negative to positive values, a prominent maximum of cathodic current appears on the curve near 0 V. The effect is explained as due to catalytic evolution of hydrogen on the electrode initially covered by adsorbed Au-hydroxidic layer. Once the layer dissolves in the acidic solution during the positive scan, a fast evolution of hydrogen takes place, catalysed by short-lived adsorbed gold particles. In d.c. voltammetry of dilute aqueous chloroauric acid with hanging mercury drop electrode, when potential scanning proceeds from negative to positive values, a prominent maximum of cathodic current appears on the curve near 0 V. The effect is explained as due to catalytic evolution of hydrogen on the electrode initially covered by adsorbed Au-hydroxidic layer. Once the layer dissolves in the acidic solution during the positive scan, a fast evolution of hydrogen takes place, catalysed by short-lived adsorbed gold particles.
dcterms:title
VOLTAMMETRY OF AQUEOUS CHLOROAURIC ACID WITH HANGING MERCURY DROP ELECTRODE VOLTAMMETRY OF AQUEOUS CHLOROAURIC ACID WITH HANGING MERCURY DROP ELECTRODE
skos:prefLabel
VOLTAMMETRY OF AQUEOUS CHLOROAURIC ACID WITH HANGING MERCURY DROP ELECTRODE VOLTAMMETRY OF AQUEOUS CHLOROAURIC ACID WITH HANGING MERCURY DROP ELECTRODE
skos:notation
RIV/61388955:_____/11:00377571!RIV13-GA0-61388955
n13:predkladatel
n14:ico%3A61388955
n3:aktivita
n12:P n12:Z
n3:aktivity
P(GAP206/11/1638), P(IAA400400806), P(LC06063), Z(AV0Z40400503)
n3:cisloPeriodika
7
n3:dodaniDat
n4:2013
n3:domaciTvurceVysledku
Yosypchuk, Bogdan n20:6505996
n3:druhVysledku
n10:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
239523
n3:idVysledku
RIV/61388955:_____/11:00377571
n3:jazykVysledku
n11:eng
n3:klicovaSlova
aqueous chloauric acid; voltammetry; hanging mercury drop electrode
n3:klicoveSlovo
n5:voltammetry n5:aqueous%20chloauric%20acid n5:hanging%20mercury%20drop%20electrode
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[0F2AA30105D1]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communications
n3:obor
n15:CG
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
3
n3:projekt
n9:LC06063 n9:GAP206%2F11%2F1638 n9:IAA400400806
n3:rokUplatneniVysledku
n4:2011
n3:svazekPeriodika
76
n3:tvurceVysledku
Yosypchuk, Bogdan Heyrovský, Michael Korshunov, A.
n3:wos
000292516100008
n3:zamer
n19:AV0Z40400503
s:issn
0010-0765
s:numberOfPages
8
n17:doi
10.1135/cccc2011064