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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F11%3A00361543%21RIV12-AV0-61388955
rdf:type
skos:Concept n16:Vysledek
dcterms:description
2,2-Dinitroethene-1,1-diamine (FOX-7) is a recently developed and broadly tested energetic material with high efficiency and low sensitivity. Generally, explosion is based on thermally initiated chain of intramolecular redox reactions. Recently it has been found that electrochemical reduction in aqueous solutions is also able to provoke the chain of follow-up processes leading to total decomposition of the parent substance yielding gaseous products analogously like during explosion. Similarly, results from reductive electrolysis of FOX-7 in aprotic solvents show analogous course of degradation. The first transferred electron activates the molecule and initiated the formation of colored radical intermediates that have been spectroscopically characterized 2,2-Dinitroethene-1,1-diamine (FOX-7) is a recently developed and broadly tested energetic material with high efficiency and low sensitivity. Generally, explosion is based on thermally initiated chain of intramolecular redox reactions. Recently it has been found that electrochemical reduction in aqueous solutions is also able to provoke the chain of follow-up processes leading to total decomposition of the parent substance yielding gaseous products analogously like during explosion. Similarly, results from reductive electrolysis of FOX-7 in aprotic solvents show analogous course of degradation. The first transferred electron activates the molecule and initiated the formation of colored radical intermediates that have been spectroscopically characterized
dcterms:title
Electrochemical and spectrometric study of FOX-7 in aprotic solvents Electrochemical and spectrometric study of FOX-7 in aprotic solvents
skos:prefLabel
Electrochemical and spectrometric study of FOX-7 in aprotic solvents Electrochemical and spectrometric study of FOX-7 in aprotic solvents
skos:notation
RIV/61388955:_____/11:00361543!RIV12-AV0-61388955
n16:predkladatel
n17:ico%3A61388955
n3:aktivita
n4:Z n4:P
n3:aktivity
P(ME09002), Z(AV0Z40400503)
n3:dodaniDat
n6:2012
n3:domaciTvurceVysledku
n10:5366976 n10:1911554 n10:4441613
n3:druhVysledku
n12:D
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
197020
n3:idVysledku
RIV/61388955:_____/11:00361543
n3:jazykVysledku
n8:eng
n3:klicovaSlova
electrolysis; polarography; FOX-7
n3:klicoveSlovo
n14:electrolysis n14:polarography n14:FOX-7
n3:kontrolniKodProRIV
[82E5F32C4F8B]
n3:mistoKonaniAkce
Jetřichovice
n3:mistoVydani
Ústí nad Labem
n3:nazevZdroje
Sborník přednášek. XXXI. Moderní elektrochemické metody
n3:obor
n22:CG
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n20:ME09002
n3:rokUplatneniVysledku
n6:2011
n3:tvurceVysledku
Šimková, Ludmila Klíma, Jiří Ludvík, Jiří
n3:typAkce
n18:WRD
n3:zahajeniAkce
2011-05-23+02:00
n3:zamer
n11:AV0Z40400503
s:numberOfPages
4
n13:hasPublisher
BEST servis
n15:isbn
978-80-254-9634-3