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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F11%3A00361465%21RIV12-AV0-61388955
rdf:type
n6:Vysledek skos:Concept
dcterms:description
The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one of the two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites. The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one of the two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites.
dcterms:title
Vinyl-ruthenium entities as markers for intramolecular electron transfer processes Vinyl-ruthenium entities as markers for intramolecular electron transfer processes
skos:prefLabel
Vinyl-ruthenium entities as markers for intramolecular electron transfer processes Vinyl-ruthenium entities as markers for intramolecular electron transfer processes
skos:notation
RIV/61388955:_____/11:00361465!RIV12-AV0-61388955
n6:predkladatel
n19:ico%3A61388955
n3:aktivita
n7:P n7:Z
n3:aktivity
P(KAN100400702), P(LD11086), Z(AV0Z40400503)
n3:cisloPeriodika
1
n3:dodaniDat
n10:2012
n3:domaciTvurceVysledku
n15:3953084
n3:druhVysledku
n4:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
238463
n3:idVysledku
RIV/61388955:_____/11:00361465
n3:jazykVysledku
n16:eng
n3:klicovaSlova
ruthenium; vinyl complexes; electrochemistry
n3:klicoveSlovo
n11:electrochemistry n11:ruthenium n11:vinyl%20complexes
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[2B921D9D7F57]
n3:nazevZdroje
Inorganica chimica acta
n3:obor
n12:CG
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n5:KAN100400702 n5:LD11086
n3:rokUplatneniVysledku
n10:2011
n3:svazekPeriodika
374
n3:tvurceVysledku
Linseis, M. Záliš, Stanislav Mücke, P. Winter, R. F.
n3:wos
000292962900006
n3:zamer
n14:AV0Z40400503
s:issn
0020-1693
s:numberOfPages
16
n9:doi
10.1016/j.ica.2011.03.071