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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F11%3A00359555%21RIV12-GA0-61388955
rdf:type
skos:Concept n16:Vysledek
dcterms:description
The topic of ambient gas analysis has been rapidly developed in the last few years with the evolution of the exciting new techniques such as DESI, DART and EESI. The essential feature of all is that analysis of trace gases can be accomplished either in the gas phase or those released from surfaces, crucially avoiding sample collection or modification. In this regard, selected ion flow tube mass spectrometry, SIFT-MS, also performs ambient analyses both accurately and rapidly. In this focused review we describe the underlying ion chemistry underpinning SIFT-MS through a discourse on the reactions of different classes of organic and inorganic molecules with H3O+, NO+ and O-2(+center dot) studied using the SIFT technique. Rate coefficients and ion products of these reactions facilitate absolute SIFT-MS analyses and can also be useful for the interpretation of data obtained by the other ambient analysis methods mentioned above. The topic of ambient gas analysis has been rapidly developed in the last few years with the evolution of the exciting new techniques such as DESI, DART and EESI. The essential feature of all is that analysis of trace gases can be accomplished either in the gas phase or those released from surfaces, crucially avoiding sample collection or modification. In this regard, selected ion flow tube mass spectrometry, SIFT-MS, also performs ambient analyses both accurately and rapidly. In this focused review we describe the underlying ion chemistry underpinning SIFT-MS through a discourse on the reactions of different classes of organic and inorganic molecules with H3O+, NO+ and O-2(+center dot) studied using the SIFT technique. Rate coefficients and ion products of these reactions facilitate absolute SIFT-MS analyses and can also be useful for the interpretation of data obtained by the other ambient analysis methods mentioned above.
dcterms:title
Ambient analysis of trace compounds in gaseous media by SIFT-MS Ambient analysis of trace compounds in gaseous media by SIFT-MS
skos:prefLabel
Ambient analysis of trace compounds in gaseous media by SIFT-MS Ambient analysis of trace compounds in gaseous media by SIFT-MS
skos:notation
RIV/61388955:_____/11:00359555!RIV12-GA0-61388955
n16:predkladatel
n17:ico%3A61388955
n4:aktivita
n9:Z n9:P
n4:aktivity
P(GA202/09/0800), P(GA203/09/0256), Z(AV0Z40400503)
n4:cisloPeriodika
10
n4:dodaniDat
n12:2012
n4:domaciTvurceVysledku
n18:9912479
n4:druhVysledku
n15:J
n4:duvernostUdaju
n6:S
n4:entitaPredkladatele
n19:predkladatel
n4:idSjednocenehoVysledku
185342
n4:idVysledku
RIV/61388955:_____/11:00359555
n4:jazykVysledku
n14:eng
n4:klicovaSlova
ion-flow tube; mass spectrometry; SIFT-MS
n4:klicoveSlovo
n5:mass%20spectrometry n5:SIFT-MS n5:ion-flow%20tube
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[B923EE0D9AB4]
n4:nazevZdroje
Analyst
n4:obor
n20:CF
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
2
n4:projekt
n13:GA203%2F09%2F0256 n13:GA202%2F09%2F0800
n4:rokUplatneniVysledku
n12:2011
n4:svazekPeriodika
136
n4:tvurceVysledku
Španěl, Patrik Smith, D.
n4:wos
000289896000001
n4:zamer
n8:AV0Z40400503
s:issn
0003-2654
s:numberOfPages
24
n7:doi
10.1039/c1an15082k