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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F11%3A00359151%21RIV12-GA0-61388955
rdf:type
n9:Vysledek skos:Concept
dcterms:description
The catalytic effect of tetraphenylporphyrin on the oxygen reduction with ferrocene in 1,2-dichloroethane can be finely tuned by varying the molar ratio of the acid to the catalyst present in the solution. The mechanism involves binding of molecular oxygen to the protonated free porphyrin base, in competition with ion pairing between the protonated base and the acid anion present. The catalytic effect of tetraphenylporphyrin on the oxygen reduction with ferrocene in 1,2-dichloroethane can be finely tuned by varying the molar ratio of the acid to the catalyst present in the solution. The mechanism involves binding of molecular oxygen to the protonated free porphyrin base, in competition with ion pairing between the protonated base and the acid anion present.
dcterms:title
Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction
skos:prefLabel
Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction
skos:notation
RIV/61388955:_____/11:00359151!RIV12-GA0-61388955
n9:predkladatel
n14:ico%3A61388955
n3:aktivita
n8:Z n8:P
n3:aktivity
P(GAP208/11/0697), Z(AV0Z40400503)
n3:cisloPeriodika
19
n3:dodaniDat
n6:2012
n3:domaciTvurceVysledku
n5:5904196 n5:9949178 n5:1415840 n5:2681544 n5:3953084
n3:druhVysledku
n17:J
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
199778
n3:idVysledku
RIV/61388955:_____/11:00359151
n3:jazykVysledku
n15:eng
n3:klicovaSlova
porphyrins; catalytic effects
n3:klicoveSlovo
n18:catalytic%20effects n18:porphyrins
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[DF6778A522A1]
n3:nazevZdroje
Chemical Communications
n3:obor
n16:CG
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
7
n3:projekt
n4:GAP208%2F11%2F0697
n3:rokUplatneniVysledku
n6:2011
n3:svazekPeriodika
47
n3:tvurceVysledku
Girault, H. H. Trojánek, Antonín Langmaier, Jan Šebera, Jakub Barbe, J.-M. Samec, Zdeněk Záliš, Stanislav
n3:wos
000289899600013
n3:zamer
n20:AV0Z40400503
s:issn
1359-7345
s:numberOfPages
3
n13:doi
10.1039/C1CC11075F