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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F10%3A00346595%21RIV11-GA0-61388955
rdf:type
skos:Concept n17:Vysledek
dcterms:description
The high resolution absorption spectrum of methane has been recorded at liquid nitrogen temperature by differential absorption spectroscopy between 6717 and 7351 cm(-1) (1.49-1.36 mu m) using a cryogenic cell and a series of distributed feed back (DFB) diode lasers. The investigated spectral region corresponds to the very congested low energy part of the icosad for which the HITRAN database provides neither rovibrational assignments nor the lower state energies. The positions and strengths at 81 K of 9389 transitions were obtained from the spectrum analysis. The minimum value of the measured line intensities (at 81 K) is on the order of 10(-26) cm/molecule. From the variation of the line strength between 81 K and 296 K, the low energy values of a total of 4646 transitions were determined. They represent 79.4% and 68.4% of the total absorbance in the region at 81 and 296 K. respectively, and include 28 transitions assigned to the nu(2)+4 nu(4) band near 6765 cm(-1). The high resolution absorption spectrum of methane has been recorded at liquid nitrogen temperature by differential absorption spectroscopy between 6717 and 7351 cm(-1) (1.49-1.36 mu m) using a cryogenic cell and a series of distributed feed back (DFB) diode lasers. The investigated spectral region corresponds to the very congested low energy part of the icosad for which the HITRAN database provides neither rovibrational assignments nor the lower state energies. The positions and strengths at 81 K of 9389 transitions were obtained from the spectrum analysis. The minimum value of the measured line intensities (at 81 K) is on the order of 10(-26) cm/molecule. From the variation of the line strength between 81 K and 296 K, the low energy values of a total of 4646 transitions were determined. They represent 79.4% and 68.4% of the total absorbance in the region at 81 and 296 K. respectively, and include 28 transitions assigned to the nu(2)+4 nu(4) band near 6765 cm(-1).
dcterms:title
Temperature dependence of the absorption spectrum of CH4 by high resolution spectroscopy at 81 K: (II) The icosad region (1.49-1.30 mu m) Temperature dependence of the absorption spectrum of CH4 by high resolution spectroscopy at 81 K: (II) The icosad region (1.49-1.30 mu m)
skos:prefLabel
Temperature dependence of the absorption spectrum of CH4 by high resolution spectroscopy at 81 K: (II) The icosad region (1.49-1.30 mu m) Temperature dependence of the absorption spectrum of CH4 by high resolution spectroscopy at 81 K: (II) The icosad region (1.49-1.30 mu m)
skos:notation
RIV/61388955:_____/10:00346595!RIV11-GA0-61388955
n3:aktivita
n6:Z n6:P
n3:aktivity
P(GA202/09/0800), Z(AV0Z40400503)
n3:cisloPeriodika
9
n3:dodaniDat
n5:2011
n3:domaciTvurceVysledku
n10:9543376 n10:8858586
n3:druhVysledku
n16:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
292189
n3:idVysledku
RIV/61388955:_____/10:00346595
n3:jazykVysledku
n14:eng
n3:klicovaSlova
methane; CH4; absorption spectroscopy
n3:klicoveSlovo
n13:CH4 n13:methane n13:absorption%20spectroscopy
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[3016F7AE8EF8]
n3:nazevZdroje
Journal of Quantitative Spectroscopy and Radiative Transfer
n3:obor
n15:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:projekt
n9:GA202%2F09%2F0800
n3:rokUplatneniVysledku
n5:2010
n3:svazekPeriodika
111
n3:tvurceVysledku
Wang, L. Mašát, Milan Kassi, S. Campargue, A. Votava, Ondřej
n3:wos
000277469800009
n3:zamer
n18:AV0Z40400503
s:issn
0022-4073
s:numberOfPages
11